Rates And Equillibria Flashcards
(18 cards)
What is collision theory?
Collision theory states that chemical reactions only occur when particles collide with each other and sufficient energy- reach activation energy
Which factors affect the rate of reaction?
- Concentration of solutions
- Temperature
- Presence of catalysts
- Surface area
- Pressure of gases
These factors influence the frequency and effectiveness of collisions between reacting particles.
How does increasing concentration affect the rate of reaction?
increases the rate of reaction because there will be more frequent successful collisions, due to more particles present in a given volume
How does increasing temperature affect the rate of reaction?
increases the rate of reaction because particles gain kinetic energy so they move faster with more energy, leading to more collisions and a higher likelihood of achieving activation energy
How does adding a catalyst affect the rate of reaction?
Increases the rate of reaction by lowering the activation energy needed for the reaction, providing an alternative route for the reaction, increasing the number of effective collisions
How does increasing surface area affect the rate of reaction?
increases the rate of reaction because more of the surface is exposed and collide, leading to more effective collisions
How does increasing pressure affect the rate of reaction?
increases the rate of reaction because the volume is reduced and concentration increases, meaning particles are more compact together, resulting in more successful collisions.
If the temperature is increased at equilibrium, the products will:
Products will increase for endothermic reaction
Products will decrease for exothermic reaction
If the temperature is decreased at equilibrium, the products will:
Products will decrease for endothermic reaction
Products will increase for exothermic reaction
What do the amount of products and reactants depend on
The conditions of the reaction (e.g. concentration, temperature, pressure
What is Le Chateliers principle?
If there is a change in the conditions of a system, the equilibrium will shift to counteract the change
3 factors that affect the position of equilibria
Concentration, temperature, pressure in gases
How does increasing temp affect position of equilibria?
Increasing, makes reaction go in the endothermic direction
Decreasing, makes reaction go in the exothermic
How does increasing pressure affect position of equilibria?
Only had effect if: gaseous state, different number of molecules on each side
Increasing, shifts to side with fewer moles of gas
Decreases, shifts to side with more moles of gas
How does increasing concentration affect position of equilibria?
Increasing, shifts away from substance you have added
Decreasing, shifts towards substance you have added
How does adding a catalyst affect position of equilibria?
No effect on position because it speeds up both forward and backward reaction by same amount
What is a catalyst and how does it work?
Catalysts are biological enzymes which increase the rate of reaction by providing a different pathway (lowering activation the energy) without being used up
What is activation energy
The minimum amount of energy that particles must have to react