Rates And Equillibria Flashcards

(18 cards)

1
Q

What is collision theory?

A

Collision theory states that chemical reactions only occur when particles collide with each other and sufficient energy- reach activation energy

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2
Q

Which factors affect the rate of reaction?

A
  • Concentration of solutions
  • Temperature
  • Presence of catalysts
  • Surface area
  • Pressure of gases

These factors influence the frequency and effectiveness of collisions between reacting particles.

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3
Q

How does increasing concentration affect the rate of reaction?

A

increases the rate of reaction because there will be more frequent successful collisions, due to more particles present in a given volume

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4
Q

How does increasing temperature affect the rate of reaction?

A

increases the rate of reaction because particles gain kinetic energy so they move faster with more energy, leading to more collisions and a higher likelihood of achieving activation energy

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5
Q

How does adding a catalyst affect the rate of reaction?

A

Increases the rate of reaction by lowering the activation energy needed for the reaction, providing an alternative route for the reaction, increasing the number of effective collisions

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6
Q

How does increasing surface area affect the rate of reaction?

A

increases the rate of reaction because more of the surface is exposed and collide, leading to more effective collisions

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7
Q

How does increasing pressure affect the rate of reaction?

A

increases the rate of reaction because the volume is reduced and concentration increases, meaning particles are more compact together, resulting in more successful collisions.

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8
Q

If the temperature is increased at equilibrium, the products will:

A

Products will increase for endothermic reaction
Products will decrease for exothermic reaction

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9
Q

If the temperature is decreased at equilibrium, the products will:

A

Products will decrease for endothermic reaction
Products will increase for exothermic reaction

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10
Q

What do the amount of products and reactants depend on

A

The conditions of the reaction (e.g. concentration, temperature, pressure

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11
Q

What is Le Chateliers principle?

A

If there is a change in the conditions of a system, the equilibrium will shift to counteract the change

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12
Q

3 factors that affect the position of equilibria

A

Concentration, temperature, pressure in gases

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13
Q

How does increasing temp affect position of equilibria?

A

Increasing, makes reaction go in the endothermic direction
Decreasing, makes reaction go in the exothermic

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14
Q

How does increasing pressure affect position of equilibria?

A

Only had effect if: gaseous state, different number of molecules on each side
Increasing, shifts to side with fewer moles of gas
Decreases, shifts to side with more moles of gas

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15
Q

How does increasing concentration affect position of equilibria?

A

Increasing, shifts away from substance you have added
Decreasing, shifts towards substance you have added

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16
Q

How does adding a catalyst affect position of equilibria?

A

No effect on position because it speeds up both forward and backward reaction by same amount

17
Q

What is a catalyst and how does it work?

A

Catalysts are biological enzymes which increase the rate of reaction by providing a different pathway (lowering activation the energy) without being used up

18
Q

What is activation energy

A

The minimum amount of energy that particles must have to react