Rates Of Reaction Flashcards

(17 cards)

0
Q

Conditions for cracking

A

Catalyst - zeolite

Temperature - 450

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1
Q

Two economically important processes that uses catalyst

A

Harber process - iron catalyst

Cracking - zeolite catalyst

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2
Q

Conditions for haber process

A

Catalyst - iron
Temperature - 400-500
Pressure - 200atm

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3
Q

Le Chatelier’s principle

A

In dynamic equilibrium the position of equilibrium shifts to counteract change

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4
Q

What is a Catalyst

A

A substance that increases rate of reaction but is not used up

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5
Q

Factors that affects the Position of equilibrium

A

Temperature
Pressure - moles
Concentration

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6
Q

Why doesn’t a Catalyst affect the position of equilibrium?

A

Because it increases the rate of forward and reverse reaction

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7
Q

Dynamic equilibrium

A

Equilibrium that exist in a close system where the rate of forward reaction in equal to rate of reverse reaction

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8
Q

What does the Boltzmann distribution show

A

The distribution of particle energies at a particular temperature

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9
Q

What are the features of the Boltzmann distribution

A
  • Under the curve show the total number of particles in the reaction and does not change with different conditions
  • no molecules have 0 energy
  • there is no maximum energy so curve does not touch axis
  • only particles pass activation energy can react
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10
Q

ROR collision theory - factories that affect rate of reaction

A
Temperature 
Pressure
Concentration
Surface area
Adding a catalyst
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11
Q

Hess law

A

A reaction could take place through more than one route, with the initial and final conditions being the same

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12
Q

Enthalpy cycle - combustion

A

B - C = A

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13
Q

Enthalpy cycle - formation

A

-B + C = A

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14
Q

Enthalpy change of combustion

A

Enthalpy change that takes place when one mole of a substance reacts completely with oxygen under standard conditions

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15
Q

Enthalpy change of formation

A

Enthalpy change that takes place when one mole of a compound in it’s standard state is formed from it’s constituent elements in their standard states under standard conditions

16
Q

Enthalpy change of reaction

A

Enthalpy change that accompanies a reaction in the molar quantities expressed in a chemical equation under standard conditions