Rates Of Reaction Flashcards
(17 cards)
Conditions for cracking
Catalyst - zeolite
Temperature - 450
Two economically important processes that uses catalyst
Harber process - iron catalyst
Cracking - zeolite catalyst
Conditions for haber process
Catalyst - iron
Temperature - 400-500
Pressure - 200atm
Le Chatelier’s principle
In dynamic equilibrium the position of equilibrium shifts to counteract change
What is a Catalyst
A substance that increases rate of reaction but is not used up
Factors that affects the Position of equilibrium
Temperature
Pressure - moles
Concentration
Why doesn’t a Catalyst affect the position of equilibrium?
Because it increases the rate of forward and reverse reaction
Dynamic equilibrium
Equilibrium that exist in a close system where the rate of forward reaction in equal to rate of reverse reaction
What does the Boltzmann distribution show
The distribution of particle energies at a particular temperature
What are the features of the Boltzmann distribution
- Under the curve show the total number of particles in the reaction and does not change with different conditions
- no molecules have 0 energy
- there is no maximum energy so curve does not touch axis
- only particles pass activation energy can react
ROR collision theory - factories that affect rate of reaction
Temperature Pressure Concentration Surface area Adding a catalyst
Hess law
A reaction could take place through more than one route, with the initial and final conditions being the same
Enthalpy cycle - combustion
B - C = A
Enthalpy cycle - formation
-B + C = A
Enthalpy change of combustion
Enthalpy change that takes place when one mole of a substance reacts completely with oxygen under standard conditions
Enthalpy change of formation
Enthalpy change that takes place when one mole of a compound in it’s standard state is formed from it’s constituent elements in their standard states under standard conditions
Enthalpy change of reaction
Enthalpy change that accompanies a reaction in the molar quantities expressed in a chemical equation under standard conditions