Reaction: Active Species+ Regioselectivity +Stereoselectivity Flashcards
1
Q
Hydrogenation
A
AS: H-H
RS: N/A
SS:Syn
2
Q
Hydrohalogenation
A
AS: H-X
RS: Markov
SS: N/A
3
Q
Hydrobromination in peroxides
A
AS: H-Br
RS: Anti-Markov
SS: N/A
4
Q
Acid-catalyzed hydration
A
AS: H-OH
RS: Markov
SS: N/A
5
Q
Oxymercuration-demercuration
A
AS: H-OH
RS: Markov
SS: N/A
6
Q
Hydroboration-oxidation
A
AS: H-OH
RS: Anti-Markov
SS: Syn
7
Q
Halogenation
A
AS: X-X
RS: N/A
SS: Anti
8
Q
Mixed-halogenation
A
AS: X-Y
RS: “Markov” (higher up table -> more subs)
SS: Anti
9
Q
Halohydrin formation
A
AS: X-OH
RS: “Markov”
SS: Anti
10
Q
Dihydroxylation
A
AS: HO-OH
RS: N/A
SS: Syn
11
Q
Epoxidation
A
AS: O
RS: N/A
SS: Syn
