Reaction: Alcohol Flashcards
(14 cards)
1
Q
Cyclopentanol –> cyclohexene + H2O
A
Reaction: acidic dehydration of alcohol
Reagent: H2SO4 or H3PO4 + heat
Product: alkene
Specifity: E1 reaction, possible rearrangement and follows Zaitsev rule
3° and 2° > 1°
2
Q
Alcohol to aldehyde
A
Reaction: oxidation to aldehyde
Reagent: PCC
Product: ALDEHYDE
Specifity: 1° Alcohol
Mild oxidation, stops at aldehyde
3
Q
Oxidation to ketone
A
Reaction: oxidation to ketone
Reagent: PCC or CrO3
Product: ketone
Specifity: 2° (3° lacks a hydrogen)
mild/strong oxidation
4
Q
Oxidation to acid
A
5
Q
Reaction with HX
A
6
Q
Lucas Test
A
7
Q
Tosylation
A
8
Q
Fischer Esterification
A
9
Q
Reaction with acyl chloride
A
10
Q
reaction with Sodium
A
11
Q
Williamson Ether Synthesis
A
12
Q
Pinacol rearrangement
A
13
Q
Sylyl protection of OH
A
14
Q
Ether cleavage
A
