reactions of amines Flashcards
(15 cards)
amine + acid =
ammonium salt
condition for the Reaction of Amines with Acids
mix at room temp
is the salt produced from the amine and acid more or less soluble than amine reactant
more
what can amines act as
ligands, nucleophiles and bases
amines acting as ligands is similar to…
ligand exchange
what type of reaction do amines and halogenoalkanes undergo
nucleophilic substitution
what is the reagent for the reaction of amines and halogenoalkanes
Halogenoalkanes (dissolved in ethanol solvent)
what is the condition for the reaction of amines and halogenoalkanes
heat under reflux
what are the products for the reaction of amines and halogenoalkanes
Secondary Amine, Tertiary Amine or Quaternary Ammonium Salt
why can the secondary amine formed undergo further nucleophilic substitution
as the lone pair in Nitrogen is stabilised and more reactive, due to more electron releasing alkyl groups
what are 2 ways to form aliphatic amines from
halogenoalkanes and nitriles
halogenoalkane + ammonia =
primary amines
what is the reagent for halogenoalkane + ammonia reaction
Excess NH3 (dissolved in ethanol solvent)
what is the condition for halogenoalkane + ammonia reaction
Heat under pressure in sealed tube