reactions of amines Flashcards

(15 cards)

1
Q

amine + acid =

A

ammonium salt

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2
Q

condition for the Reaction of Amines with Acids

A

mix at room temp

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3
Q

is the salt produced from the amine and acid more or less soluble than amine reactant

A

more

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4
Q

what can amines act as

A

ligands, nucleophiles and bases

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5
Q

amines acting as ligands is similar to…

A

ligand exchange

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6
Q

what type of reaction do amines and halogenoalkanes undergo

A

nucleophilic substitution

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7
Q

what is the reagent for the reaction of amines and halogenoalkanes

A

Halogenoalkanes (dissolved in ethanol solvent)

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8
Q

what is the condition for the reaction of amines and halogenoalkanes

A

heat under reflux

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9
Q

what are the products for the reaction of amines and halogenoalkanes

A

Secondary Amine, Tertiary Amine or Quaternary Ammonium Salt

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10
Q

why can the secondary amine formed undergo further nucleophilic substitution

A

as the lone pair in Nitrogen is stabilised and more reactive, due to more electron releasing alkyl groups

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11
Q

what are 2 ways to form aliphatic amines from

A

halogenoalkanes and nitriles

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12
Q

halogenoalkane + ammonia =

A

primary amines

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13
Q

what is the reagent for halogenoalkane + ammonia reaction

A

Excess NH3 (dissolved in ethanol solvent)

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14
Q

what is the condition for halogenoalkane + ammonia reaction

A

Heat under pressure in sealed tube

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15
Q
A
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