Reactions to know Flashcards
(58 cards)
Alkane –> Halogenoalkane conditions
X2 and UV light
Alkane –> Halogenoalkane reagents and reaction
hydrogen halide, electrophilic addition
problem with radical substitution
-substitution can take place anywhere on the carbon chain so structural isomers
-a mixture of products can be formed due to having excess halogen radicals
Alkene –> Alkane conditions
H2, Ni catalyst, 150 degrees C
Alkene –> Alkane reaction
electrophilic addition/ hydrogenation
Alkene –> Di halogenoalkanes reagents and conditions
halogen, 20 degrees C
Alkene –> Di halogenoalkane reaction and test
electrophilic addition, brown Br2 water decolourised
Alkene –> Alcohol reagents and conditions
hydrated by steam, at 300 degrees C, pressure 60-70 atm, solid phosphoric acid catalyst
Alkene –> Alcohol reaction
hydration
Alkene –> Diol reagents and conditions
shake alkene with acidified potassium manganate (VII) the purple solution is decolourised, 20 degrees C
Alkene –> Diol reaction
oxidation reaction
Alkene –> Halogenoalkane reagents
hydrogen halides, 20 degrees C
Alkene –> Halogenoalkane reaction
addition reaction
Alkene –> Halogenoalkane problems
hydrogen halides react with unsymmetrical alkenes 2 products form depending on the strength of the carbon cat ion
Halogenoalkane –> Alcohol reagents
using KOH under reflux OR
Mg, dry ether, a carbonyl dilute acid
Halogenoalkanes –> Alcohols reaction
nucleophilic substitution
Halogenoalkanes –> Nitriles reagent and conditions
under reflux, potassium cyanide in ethanol
Halogenoalkanes –> Nitriles reaction
nucleophilic substitution
Halogenoalkanes –> Amines reagents and conditions
ammonia, warm halogenoalkane and XS ethanolic ammonia, heat
Halogenoalkanes –> Amines reaction
nucleophilic substitution
Halogenoalkanes –> Alkenes reagents and conditions
KOH dissolved in ethanol, heated under reflux
Halogenoalkanes –> Carboxylic Acid reagents
Mg, dry ether then CO2 then dilute acid
Alcohols –> Halogenoalkane reagents and conditions
PCl5/HCl for chloroalkanes, 20 degrees C,
KBr, 50% concentrated H2SO4, 20 degrees C for bromoalkane
PI3 by refluxing alcohol with red phosphorus and I2 for iodoalkane
Alcohols –> Halogenoalkane reaction
substitution reaction