Reactivity 3.1 Flashcards
(31 cards)
Ionic/Arrhenius theory
Acids are substances that dissociate in aqueous solution to produce H+ ions (protons)
What happens when protons combined with water?
Hydronium ions are formed (H3O+)
How can an acid be neutralised?
By a base to form salt or water
Alkali
Soluble bases which form OH- in solution
Bronsted Lowry theory
An acid is a substance that can donate a proton and a base is a substance that can accept a proton
Amphoteric
Can act as an acid or base
When Bronsted Lowry acid loses a proton,
It forms a conjugate base
Conjugate acid-base pair
Differs by a single proton H+
pH scale
Measure of the hydrogen ion concentration in aqueous solution
pH when volume or dilution
pH value is independent of volume of solution. Changes when diluted.
pH logarithmic scale
A change of one unit of pH represents a change by 10x in the hydrogen ion concentration
Kw
Ionic product constant for water
Monoprotic acids
Contain one acidic hydrogen atom (acid concentration = hydrogen concentration)
Diprotic acids
Contains two acidic hydrogen atom (hydrogen concentration = 2x acid concentration)
Two ways to determine pH value of solution
Universal indicator and a pH meter.
Strong acids in aqueous solution
Completely dissociate into their ions
Weak acids in aqueous solution
Partially dissociate into their ions, the weaker the acid/base, the less degree of dissociation
Ka
Acid dissociation constant. The smaller the value of k, the weaker the acid.
Electrical conductivity (strong vs weak acids)
The stronger the acid/base, the high the electrical conductivity.
pH (strong vs weak acids)
The stronger the acid, the lower the pH (compared to the pH of a weak acid of the same concentration)
Chemical reactivity (weak and storng acids)
Acids react with metals to produce H2 gas and undergo neutralisation with metals. Weaker acids have lower reaction rates.
Strong acids - conjugate base
Weak conjugate bases as acid has fully dissociated. Little tendency to gain a proton
Weak acids - conjugate bases
Easily accepts protons from water
Acids neutralisation
Reacting with a base to form salt and water. Exothermic.