Reation Pathways - Aliphatic Compunds Flashcards by Ben Hallam

Q

Alkene → Alkane

A

H2/Ni, 150°C

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Q

Alkene → Haloalkane

A

Hydrogen Halide, 20°C

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Q

Alkane → Haloalkane

A

Halogen UV Light

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Q

Haloalkane → Nitrile

A

CN-/Ethanol, reflux

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Q

Haloalkane → Amine

A

NH3/Ethanol, heat

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Q

Haloalkane → Alcohol

A

NaOH(aq), H2O, reflux

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Q

Alcohol → Haloalkane

A

Sodium Halide/H2SO4, 20°C

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Q

Alkene → Alcohol

A

H2O (Steam)/H3PO4, 300°C, 60-70 atm

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Q

Alcohol → Alkene

A

Conc. H3PO4 or H2SO4, 170°C

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Q

Alcohol → Ester

A

Carboxylic Acid/Conc. H2SO4 OR Acid Anhydride

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Q

Ester → Alcohol

A

Dilute acid, reflux

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Q

1° Alcohol → Aldehyde

A

K2Cr2O7/H2SO4 distillation

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Q

Aldehyde → 1° Alcohol

A

NaBH4

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Q

1° Alcohol → Carboxylic Acid

A

K2Cr2O7/H2SO4 reflux

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Q

Aldehyde → Carboxylic Acid

A

K2Cr2O7/H2SO4 reflux

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Q

Nitrile → Amine

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A

H2/Ni

Q

2° Alcohol → Ketone

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A

K2Cr2O7/H2SO4, reflux

Q

Ketone → 2° Alcohol

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A

NaBH4

Q

Ketone → Hydroxynitrile

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A

NaCN(aq)/H+(aq)

Q

Aldehyde → Hydroxynitrile

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A

NaCN(aq)/H+(aq)

Q

Hydroxynitrile → Amine

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A

H2/Ni

Q

Nitrile → Carboxylic Acid

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A

H2O/HCl, reflux

Q

Hydroxynitrile → Carboxylic Acid

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A

H2O/HCl, reflux

Q

Carboxylic Acid → Ester

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A

Alcohol/Conc. H2SO4, heat

Ester → Carboxylic Acid

Dilute acid, reflux

Ester → Carboxylate

OH- heat

Carboxylic Acid → Acyl Chloride

SOCl2

Acyl Chloride → Carboxylic Acid

Cold H2O

Acyl Chloride → 1° Amide

NH3, 20°C

Acyl Chloride → 2° Amide

Primary Amine, 20°C