redox Flashcards
(16 cards)
describe what oxidation is in terms of the 3 different wordings?
-gain of oxygen
-loss of electrons
-loss of hydrogen
describe what reduction is in terms of the 3 different wordings?
-loss of oxygen
-gain of electrons
-gain of hydrogen
what is a redox reaction?
when both reduction and oxidation are going on side-by-side
what do oxidising and reducing agents do?
oxidising agents are species that cause another element to be oxidised- it itself is reduced in the reaction
reducing agents are species that cause another element to be reduced- it itself is oxidised in the reaction
what are the rules for assigning oxidation states? (4 rules)
- on simple ions, the oxidation state is equal to the charge on the ion
- in elements, the oxidation state is always zero
- the total of all oxidation states must always equal the overall charge of the species
- in molecules and more complex ions, the more electronegative element is assumed to be the negative ion
what is the oxidation state of group 1, 2 and 3 metals?
+1, +2, +3
what is the oxidation state of F?
-1
what is the oxidation state of Cl, Br and I?
-1 except in compounds with oxygen and flourine
what is the oxidation state of Oxygen?
-2 except in peroxides where it is -1 and in compounds with flourine
give the list of decreasing priority when it comes to assigning priority for oxidation states?
1
2
3
F
H
O
Cl
what does a reduction half equation show?
only shows the parts of a chemical reaction involved in reduction
electrons are on left
what does an oxidation half equation show?
only the parts of a chemical equation involved in oxidation
the electrons are on the right
what do oxidising and reducing agents act as?
oxidising agents are electron acceptors
reducing agents are electron donors
what is the step by step process for writing half equations?
- work out oxidation numbers for element being oxidised/ reduced
- add electrons to equal the change in oxidation number
- check to see that the sum of the charges on the reactant side equals the sum of the charges on the product side
what do we do to half equations when the substance that is being oxidised/ reduced contains a varying amount of O?
balance half equations by adding H+, OH- ions and H2O
what must be the case in order to combine two half equations?
there must be equal numbers of electrons in the two half equations so that the electrons cancel out
you can multiply the half equations to get equal electrons