Redox Flashcards
(29 cards)
Voltaic cell converts ___ to _____
Chemical energy to electrical energy
What happens when electrolytes dissolve in water
They conduct electrical current
Electrolytic cells covert ___ to _____
Electrical energy to chemical energy
Electrodes=
Conductors that carry electrons in and out of the cell
Formula for voltage of the cell
Electrical potential of cell= EP cathode - EP anode
Anode is oxidized therefore it becomes ____
Smaller
Cathode is reduced therefore it ____
Gains mass
Anions go to the ____ and cations go to the ____
Anode
cathode
If the EPcell is > 0 the rxn is ___
Spontaneous
If EPcell < 0 the rxn is ____
Non spontaneous
Anode has a __ charge ad cathode has a ___ charge
- +
If cl2 is present what colour does litmus paper turn
White
Primary batteries=
Runs until it runs out then you throw it away
Secondary batteries s=
rechargeable batteries
Fuel cells=
Voltaic cells that can be refueled by adding fuel 1st
4 ways to prevent corrosion
1) paint or other coatings
2) forming an alloy
3) galvanizing
4) cathodic protection
What’s involved in forming an alloy
Mix iron with more resistant metals in an alloy so they’re bale to resist environmental stresses better
What is galvanizing
Iron is coated with a protective layer of zinc so they’re bale zinc corrodes instead of the iron (acts as a barrier) (zinc is a sacrificial anode)
Differences in electrolytic vs. Voltaic cells
- DC power source not volt meter
- voltage should be negative indicating on spontaneous RXN
- anode is + cathode is -
- EP cell= (-)
2 components involved in cathodic protection
Sacrificial anode
Impressed current
What is the method of sacrificial anode
A more reactive metal is attached to the iron therefore that is corroded first (needs replacing occasionally)
What is impressed current
Trickles electrons through a DC power source onto the metal to protect it
In the electrolysis of molten what species isn’t present
H20
What is the chlorine anomoly
If both chlorine and h20 can be oxidized, chlorine will be oxidized first despite the reduction table