Resin Composites 1 Flashcards

(31 cards)

1
Q

what make up the resin matrix?

A

methacrylate or dimethacrylate monomers

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2
Q

what are examples of monomers

A

BISGMA

Urethane dimethacrylate

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3
Q

What are examples of co monomers?

A

TEGMA

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4
Q

What does TEGMA do?

A

controls viscosity

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5
Q

What else are present in resin composites?

A

inhibators

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6
Q

What do products based on silorane produce?

A

expansion that offsets shrinkage

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7
Q

what do c=c bonds take part in?

A

free radical polymerisation

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8
Q

What do unreacted monomers in resin composites allow for?

A

scope for chairside repair

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9
Q

What does the viscosity of the matrix polymer do?

A

reduces mobility of untreated monomers

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10
Q

What are two types of siloranes?

A

siloxanes

oxiranes

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11
Q

what do siloxanes contribute to resin composties?

A

factor of hydrophobicity

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12
Q

What do oxiranes contribute to resin composites?

A

ring opening polymerisation

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13
Q

catatonic cure?

A
camphorquinone
iodium salt
electron doner
ring opening polymerisation
allows for less shrinkage
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14
Q

what are fillers?

A

quartz
silica
glasses

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15
Q

What are glasses in resin composites?

A

aluminasilicates
bora silicate
barium oxide

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16
Q

what are coupling agents?

A

methacryloxypropyltrimethoxysilane

silane interacts and bonds with glass

17
Q

What does high filler content mean?

A

higher surface hardness

18
Q

what does high filler content mean re. volume setting contraction?

A

higher filler the lower % of volume setting contraction

19
Q

The higher filler means what to thermal expansion?

A

higher filler, the less co efficient of thermal expansion

20
Q

what does camphorquinone do re. polymerisation

A

yields necessary free radical to start polymerisation

21
Q

at what level does camphorquinone become excited?

A

40-60 nm- visable blue light

22
Q

What is blue light most readily generated by?

A

quartz halogen lights

23
Q

What is the downside to resin in composite?

A

susceptible to shrinkage upon polymerisation

24
Q

what are resins?

A

modified methacrylate/acrylate

oxirane- ring opening

25
what is the function of the filler>
shock absorber
26
What is the function of the coupling agent?
transfers stress from loading from rigid riller to more flexible and ductile matrix
27
What are the types of resin composites?
conventional- used for posterior/ occlusal restoration micro filled- anterior hybrid nano composites
28
What other properties are there to resin composite?
gradual set from outer surface | required incremental cure
29
with increased porosity?
less strength | less fatigue
30
with decreased coupling?
less strength | less fatigue
31
What is cfactor?
measure of bond strength | number of bonded surface/number of unbonded surfaces