S2.1 Ionic Flashcards

1
Q

what is isoelectronic?

A

two different species with the same electron configuration eg Mg2+ and Ne

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2
Q

what is electronegativity?

A

the ability of an atom to attract a pair of covalently bonded electrons

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3
Q

what is a lattice?

A

continuous 3d networks of repeating units of positive and negative ions

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4
Q

what is lattice enthalpy?

A

how strong the ionic bonds are in particular ionic lattice

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5
Q

ammonium ion

A

NH4+

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6
Q

nitrate ion

A

NO3-

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7
Q

hydrogencarbonate

A

HCO3-

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8
Q

why are ionic compounds usually brittle?

A

bc when a force is applied, the force displaces some ions within the lattice which means ions of the same charge are positioned next to each other. The repulsive forces between the ions cause the lattice to split

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9
Q

what are the 2 factors affecting lattice enthalpy?

A

ionic radius and ionic charge

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10
Q

the strength of the electrostatic attraction between oppositely charged ions

A

increases w increasing ionic charge; decreases w increasing ionic radius

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11
Q

what is volatility?

A

the tendency of a substance to vaporize

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12
Q

ionic compounds: volatility

A

volatility is low because for ionic compounds to turn into gases, the strong electrostatic forces of attraction holding the ions together need to be overcome

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13
Q

what are ionic compounds soluble and insoluble in?

A

soluble in polar solvents(water); insoluble in non-polar solvents(hexane)

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14
Q

carbonate ion

A

CO3 2-

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15
Q

sulfate ion

A

SO4 2-

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16
Q

phosphate ion

A

PO4 3-

17
Q

which ions would have a greater lattice enthalpy?

A

smaller ions with greater charge=greater lattice enthalpy

18
Q

what kind of process is lattice enthalpy?

A

endothermic so always negative

19
Q

why are ionic compounds soluble in polar solvents like water?

A

bc water surrounds molecule overcoming electrostatic attraction

20
Q

what happens to solubility when charge on ion increases?

A

solubility decreases bc water molecule cannot overcome forces of attraction