Save My Exams bonding Flashcards
(37 cards)
Changes of state
physical changes that are reversible
do not change the chemical properties or chemical makeup of the substances involved
Evaporation
he change of liquid to gas, but unlike boiling, evaporation occurs only at the surface and takes place at temperatures below the boiling point
Boiling
occurs at a specific temperature and takes place when the vapour pressure reaches the external atmospheric pressure
Between 1 & 2 on change of state graph
the particles are vibrating and gaining kinetic energy and the temperature rises
Between 2 & 3
all the energy goes into breaking bonds – there is no increase in kinetic energy or temperature
Between 3 & 4
particles are moving around and gaining in kinetic energy
Between 4 & 5
the substance is boiling, so bonds are breaking and there is no increase in kinetic energy or temperature
5 & 6
particles are moving around rapidly and increasing in kinetic energy
Ionic bonding
the transfer of electrons from a metallic element to a non-metallic element
Transferring electrons usually leaves the metal and the non-metal with a full outer shell
formed between the oppositely charged ions, which occurs in all directions
Electrostatic attractions
formed between the oppositely charged ions to form ionic compounds
ions form a
lattice structure which is an evenly distributed crystalline structure
regular repeating pattern so that positive charges cancel out negative charges
Each ion is attracted to all of the oppositely charged ions around it
Therefore the final lattice is overall electrically neutral
Covalent bonding
occurs between two non-metals
A covalent bond involves the electrostatic attraction between nuclei of two atoms and the bonding electrons of their outer shells
No electrons are transferred but only shared
how many electrons shared in single carbon bond
2
how many electrons shared in double carbon bonds
4
how many electrons shared triple carbon bonds
6
expanding the octet rule’
Being able to accommodate more than 8 electrons in the outer shell
electron deficient’
Accommodating less than 8 electrons in the outer shell means than the central atom is ‘electron deficient’
Dative Covalent Bonding
Some molecules have a lone pair of electrons that can be donated to form a bond with an electron-deficient atom
An electron-deficient atom is an atom that has an unfilled outer orbital
So both electrons are from the same atom
This type of bonding is called dative covalent bonding or coordinate bonding
In a dot and cross diagram:
Only the outer electrons are shown
The charge of the ion is spread evenly which is shown by using brackets
The charge on each ion is written at the top right-hand corner
Ionic compounds
Ionic bonds are formed when metal atoms transfer electrons to a non-metal to form a positively charged and negatively charged ion
The atoms achieve a noble gas configuration
Covalent compounds
The atoms in covalent compounds will share their outer valence electrons to achieve a noble gas configuration
Metallic Bonding
tightly packed together in lattice structures
electrons in their outer shells are free to move throughout the structure
‘delocalised electrons’
When the electrons are delocalised, the metal atoms become positively charged ions
The positive charges repel each other and keep the neatly arranged lattice in place
There are very strong forces between the positive metal centres and the ‘sea’ of delocalised electrons
Giant ionic lattices
When an ionic compound is formed, the attraction between the ions happens in all directions
Ionic compounds are arranged in giant ionic lattices (also called giant ionic structures)
The type of lattice formed depends on the sizes of the positive and negative ions which are arranged in an alternating fashion
The ionic lattice of MgO and NaCl are cubic
Covalent lattices
Covalent compounds can be arranged in simple molecular or giant molecular lattices
Simple molecular lattices: iodine, buckminsterfullerene (C60) and ice
Giant molecular: silicon(IV) oxide, graphite and diamond