Section 3 - Inorganic Chemistry x_x Flashcards

1
Q

group one metals

A

group one metals all react in a similar way with water
(Li, Na, K react vigorously and produce metal hydroxide alkaline solution and hydrogen -fizzing-)

react with o2
- lithuim forms lithium oxide (li2o)
- sodium forms sodium oxide (Na2O) and sodium peroxide (Na2O2)
- potasium forms potasium peroxide (K2O2) and potasium superperoxide (KO2)

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2
Q

group one properties

A

become more reactive down group (loose electrons more easlily as there is more space to nucleus)

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3
Q

halogens properties

A

as atomic number increases (go down) they are darker and have a higher boiling point

at room temp:
- chlorine is a poisonous green gas
- bromine is a poisonous red-brown liquid which gives off orange vapour at room temp
- iodine is a drak grey crystaline solid that gives of purple vapour when heated

  • higher up metal in group 7 is more reactive
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4
Q

transfer of electrons in a displacement reaction

A

a loss of electrons (oxidation) and gain of electons (reduction ) happen simultaneously (element displaced is oxidised and element taking its place is reduced)
oxidising agent accepts electrons and gets reduced
reducing agent gives away electons and gets oxidised

this is a redox reaction

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5
Q

displacement in halogens

A

???

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6
Q

gases in atmosphere

A

78% nitrogen
21% oxygen
nearly 1% noble gases
0.04% CO2

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7
Q

investigate proportion of oxygen in atmosphere

A

1) first soak iron wool in aceietic acid (calayses reaction), then push wool into measuring cylinder in beaker of water
2) record starting position of water on scale of measuring cylinder (starting volume of air)
3) over time it will rise becasue the iron reacts with oxygen to make iron oxide and water rises to fill space oxygen took up
4) leave for week and then record final position of water

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8
Q

phosphorus to determine percentage of o2 in air

A

place phosphorus in tube and attach a syringe at either end, one of them filled with air the other empty
heat pjhosphorus and use syringes to pass air over it
phosphus will react with o2 to make ohosphus oxide, so air in syringes will decrease
measure starting and final volumes of air with syringes scales and calculate oxygen percentage (s - f /s )

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9
Q

magnesium burns in air

A
  • bright white flame
  • white powder formed (magnesium oxide)
  • magensium oxide skightly alkaline dissolved in water
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10
Q

hydrogen burns in air

A
  • burns easily in oxygen, in fact can be explosive
  • almost invisible pale blue flame
  • product = water (as water vapour)
  • used to test for hydrogen gas, giving squeaky popu
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11
Q

sulfur burns in air

A
  • pale blue flame
  • produces sulfur dioxide
  • acidic when dissolved in water
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12
Q

thermal decomposition of metal carbonates

A

produces co2 and a metal oxide

thermal decomposition = subsyance breaks down into simpler substances when heated

copper(II) carbonate is a green powder that will easily decompose to form carbon dioxide and copper(II) oxide when heated
you can prove this in an experiment where you heat it and collect produced gas with test tube, which you can test to see if its co2
CuCO3 -> CuO - CO2

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13
Q

carbon diozide as a greenhouse gas

A

greenhouse gases act as an insulating layer and absorb heat that would be radiated out into space

humans make there be more co2
- deforestation
- burn fossil fuels

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14
Q

co2 leads to climate change

A

increase in co2 has casued avg temp to rise and affected weather patterns

(page 40 add info)

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15
Q

metals react with acids

A

metal + acid = salt + hydrogen

you can use this to work out how reactive a metal is (more reactive = faster reaction)
- set up 3 boiling b¡tubes and fill with equal volumes of dilute hydrochloric acid or dilute sufluric acid
- place pieces of magenesium zinc and iron in separate test tubes (size and shape between them is the same)
- speed of reaction can be indicated by rate at which bubbles are given off
- hydorgen confirmend by burning splint test (squeaky pop)
magnesium most reactive
zinc middle
iron least reactive

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16
Q

reactivity series

A

potassium
sodium
lithium
calcium
magnesium
aluminium
zinc
iron
copper
silver
gold

17
Q

displacement

A
  • more reactive takes place of least reactive, because it bonds more stringly.
  • displacement is redox reactions
  • if a reaction occurs there is change in temperature(more reactive = more temp)
18
Q

rust

A

iron + oxygen + water = hydrated iron (iii) oxide (rust)

  • rusting happens when iron is in contact with both water and oxygen
  • oxidation reaction where iorn gains electrons to form iron (III) oxide
  • water becomes loosesly bonded forming hydrated iron(III) oxide - rust
19
Q

preventing rusting (barrier)

A

barrier methods
- paint / coat with plastic - not in direct contact with iron
- oiling/ greeasing - ideal for moving oarts like bike chains

20
Q

preventing rusting (sacrificial)

A

(place a more reactive metal with the iron, therefore the water and oxygen react with this instead)

zinc
- its more reactive, so it will be oxidised instead
- coaying of zinc can be sprayed - galvanising
- bigblocks of zinc can be bolted to iron

21
Q

oxidation

A

gain of oxygen

22
Q

reduction

A

loss of oxygen

23
Q

universal indicator

A

red - yellow - acidic
green neutral
blue -purple -alkaline

24
Q

litmus paper

A

red acidic
purple neutral
blue alkaline

25
Q

phenolphthalien

A

clolourless acidic
purple alkaline

26
Q

methyl organe indicatior

A

red acidic
yellow alkaline

27
Q

acid

A

source of hydorgen ions, proton donors

28
Q

base

A

substance that can neutralise an acid, proton acceptors
alkalise - soluble bases
alkali - source of OH⁻ ions with ph greater than 7

29
Q

neutralisation

A

reaction between acid and base
H + OH = H20

30
Q

when are salts formed

A

when acids react with bases
acid + base = salyt + water

type of salt depends on acid
HCl = chloride salts
sulfuric acid = sulfate salts
nitric acid = nitrate salts

31
Q

different bases:

A

acid + metal oxide = salt + water
acid + metal hydorxide = salt + water
acid + ammnia = ammonium salt
acid + metal carbonate = salt + water + co2
acid + metal = salt + hydrogen

32
Q

rules of solubility

A

salt can be a precitpitate (insoluble) or in solution (soluble)

sodium potassium and ammonium salts = soluble
nitrates = soluble
chlorides = soluble (except silver and lead chloride)
sulfates = soluble (except lead, barrium and calcium sulfate)

carbonates = insoluble ( except sodium potassium and ammoniums)
hydroxides = insoluble (except sodium potasium and calcium)

33
Q

make a soluble salt

A

acid and insoluble base