Semester 1 Exam Flashcards

(100 cards)

1
Q

What are the 4 SHE concepts?

A

Communication and Collaboration, Development, Influence, Application and Limitation

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2
Q

Cation

A

Positively charged (Lost electrons)

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3
Q

Anion

A

Negatively charged (more electrons than protons)

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4
Q

What is the simple electron shell configuration?

A

2, 8, 8, 18, 18…

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5
Q

What does VSEPR stand for?

A

Valence (electron) Shell Electron Pair Repulsion

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6
Q

What does VSEPR do?

A

VSEPR is how molecules are most stable when the electron pairs are as far away from each other as possible.

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7
Q

Around an electron, there can be up to four ‘groups’. What is in these groups?

A

Every lone pair of electrons and each bond count as groups. There are typically four groups max per atom

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8
Q

What is covalent bonding?

A

A bond formed through non-metals sharing electrons to form a full valence shell.

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9
Q

On the Periodic table:
What does the top number (normally) represent?

A

Atomic number/Protons

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10
Q

On the Periodic table:
What does the bottom number (normally) represent?

A

Molar mass/atomic mass

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11
Q

What is a linear molecule?

A

Linear molecules are like this: X - A - X
They usually occur when the A molecule only has two electron groups. The bond angle is 180 degrees

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12
Q

How do you find how many neutrons are in a atom?

A

atomic mass - atomic number

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13
Q

How does covalent bonding occur?

A

when 2 non-metals come near each other, their valence electrons are attracted to the nucleus of both atoms and so are shared between the two.

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14
Q

What are group numbers?

A

Columns in the periodic table, show how many valence electron there in in that atom.

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15
Q

How many H atoms does O need to have a full valence shell?

A

2

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16
Q

What is a V-shaped (bent) molecule?

A

In a V-shaped molecule, the central atom has four electrons in bonds and four that aren’t. Unbonded electrons still have a negative charge, so the molecule forms a V-shape

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17
Q

how many more electrons does Nitrogen need to achieve a full valence shell, and what type of covalent bond does it have?

A

3, triple

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18
Q

What do the valence electrons determine?

A

How the atom acts and reacts in chemical reactions.

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19
Q

What are period numbers?

A

The number of electron shell there are in that atom

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20
Q

What is a trigonal pyramid molecule?

A

The central atom is surrounded by 8 electrons, 6 in bonds and 2 that are not.

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21
Q

What is a tetrahedral molecule?

A

The central atom is surrounded by 8 electrons, all of which are in bonds.

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22
Q

What is a polar molecule?

A

A molecule that has polar covalent bonds and has one end which is slightly positive, and another that is slightly negative. 🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️ :polar_bear: 🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️🐻‍❄️

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23
Q

How do you determine that a molecule is polar?
🐻‍❄️

A

Draw the electron dot diagram, apply VSEPR rules to draw the shape, and use electronegativities to determine the dipoles

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24
Q

What is the difference between intra and inter?

A

Intramolecular bonding is bonding within molecules, and intermolecular (or secondary) bonding is between molecules

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25
What is a secondary interaction/bond?
A generally weaker bond between molecules, often determining a molecules mp and bp. The stronger the bond, the higher the mp and bp
26
What are the four main secondary interactions?
In order of weakest to strongest: dispersion, dipole-dipole, hydrogen bonding, and ion-dipole.
27
What is a dispersion force?
The weakest secondary interaction, every covalent molecule has a level of dispersion between it and other molecules. The force can change depending on the shape of the molecules and the number of electrons.
28
What is a dipole-dipole interaction?
Polar molecules have negative and positive sides, which are attracted to each other. The negative side of one molecule attracts the positive side of another, so on so forth. Likely to be l or s at rt.
29
What's an ion-dipole interaction?
Idk. Miss didn't tell us. Grrrrrrrrr ok real answer: a force of interaction between a charged ion (cation/anion) and a molecule's partially charged dipoles. strongest secondary interaction occurs between particles where one has a partial electric charge (the dipole) and the other has a full charge (the ion) - khan acadmey
30
What is hydrogen bonding?
Hydrogen bonding occurs between two molecules where hydrogen is bonded to a nitrogen, oxygen or fluorine. This is because hydrogen is pathetic, and is not very electronegative. So, the more electronegative parts attract to the hydrogen and they form secondary bonds.
31
What is organic chemistry?
The study of molecules from living things. All these molecules contain carbon. It's atoms share up to 4 electron pairs, which can make complex molecular compounds: organic compounds.
32
What are the exceptions to the 'carbon is in all living things' rule?
Carbon dioxide, carbon monoxide, carbonates and cyanide. None of these have hydrogen.
33
What are hydrocarbons?
The simplest organic molecules are fuels made of only carbon and hydrogen. Their bond is non-polar, meaning they are insoluble in water.
34
What is an alkane?
Alkanes are the simplest family of hydrocarbons, only made of single bonds. Because each carbon has the max no. of hydrogen bonded to them as possible, they are saturated.
35
What are the properties of alkanes?
When alkanes get larger, the secondary bonds become stronger, and so the mp and bp increase. The larger these forces, the more viscous.
36
What is the general formula for an alkane?
C(n)H(2n+2)
37
What are the prefixes for the number of carbons?
Meth, eth, prop, but, pent, hex, hept, oct, non, dec
38
How do you name this thing? CH3-CH2-CH-CH2-CH2-CH3 | CH3 (please pretend this is attached to the first CH3 it won't let me have fun)
First, count the longest chain of carbons. Next, number the carbons in the main chain, starting at the end closest to the branch. Identify where the branch is and how many carbons are in the branch. This one would be called 1-methyl hexane
39
What is an unsaturated hydrocarbon?
To be unsaturated, the carbons in the hydrocarbon have to not have the max amount of hydrogen bonded to them. Therefore, they must have at least one double or triple bond.
40
What do you call a hydrocarbon that has at least one double bond?
Alkene!!! :D
41
What is the general formula of an alkene?
C(n)H(2n)
42
How to name alkene???
1. length of side chain and location (e.g. 2-methyl) 2. number of carbons in main chain + where the double bond is (e.g. 3-but) 3. ene 2-methyl 3-butene
43
what does the 'ene' in alkenes turn to when there are two double bonds?
diene.
44
What is combustion?
An exothermic reaction where fuel reacts with an oxidizer (normally oxygen) at high temps. This is used to realise stored energy in the fuel!!!
45
What is complete combustion?
When fuel and oxygen react, and the only products are carbon dioxide and water. This happens when there is enough oxygen.
46
covalent molecules have low mpt and bpt, true or false?
true
47
What is incomplete combustion?
Incomplete combustion is where there isn't enough oxygen for the fuel to react with, and secondary products like carbon monoxide and carbon (soot) are made. They bad grr
48
what state(s) are covalent molecules at room temp?
liquid or gas
49
In order from smallest to largest, what are the 4 sub-shell types and how many electrons are in each?
s (2), p(6), d(10), f(14)
50
what is the name of CCl4?
carbon tetrachloride
51
what is the name of N2O4?
dinitrogen tetraoxide
52
What is an alkyne?
Triple bond baby
53
how does metallic bonding occur?
metals lose electrons, forming cations and those cations are arranged in a 3D lattice. the valence electrons on each metal more freely throughout the lattice and forms a "sea of electrons".
54
how does the sea of electrons contribute to a metal's properties?
the sea of electrons makes the metal be able to conduct electricity.
55
What is the Aufbau principle?
The Aufbau principle states that an electron occupies orbitals in order from lowest energy to highest energy.
56
how does ionic bonding occur?
when a non-metal reacts with a metal, it gains an electron and forms an anion, and the metal becomes a cation. these opposite charged ions attract each other to form a lattice.
57
What is Hund's rule?
Hunds Rule states that Every orbital in a subshell is singly occupied before an orbital is doubly occupied. For simplicity, all singly occupied subshells have a up-spin electron
58
What is the Electron configuration of? Nitrogen?
1s2 2s2 2p3
59
What is the electron configuration of Titanium?
1s2 2s2 2p6 3s2 3p6 4s2 3d2
60
What are the two elements that are exceptions to Aufbau's principle
Copper (Cu) (1s2 2s2 2p6 3s2 3p6 4s1 3d10) and Chromium (Cr) (1s2 2s2 2p6 3s2 3p6 4s1 3d5)
61
How do atoms emit their emmision spectrum?
Electrons can absorb and emit electromagnetic radiation. When they absorb radiation, they move up in energy level – we call this the excited state. When they lose this energy and fall back down (ground state), they emit a photon of light energy – this is specific to each element.
62
what is polarity?
the measure of sharing of electrons within a bond
63
how does a non-polar covalent bond occur?
when 2 atoms with similar/same electronegativity (<0.4 diff) forming the bond shares the pair of electrons equally
64
how does a polar covalent bond occur?
when 2 atoms forming the bond DOESN'T share the pair of electrons equally and they have different electronegativities (>0.4 diff)
65
What is an emission Spectrum?
The wavelengths of the light that is emitted from a atom when falling from excited to ground state. (Inverse of absorption)
66
how do you know if a bond in a molecule is non-polar?
if there is no difference in charge distribution and even electron density in the electron cloud, and the atoms have little/no diff in e/n
67
how do you know if a bond is polar?
if there is a diff in charge distribution in the electron cloud, and one atom attracts more electrons than the other
68
what symbol is used to represent the different charges?
δ+ or δ- (lower case delta)
69
What is an absorption spectrum?
The waves lengths of the light that is absorbed by an atom (Inverse of emission)
70
how many particles are in 1 mole of any chemical substance?
6.02x10^23 (avogadro's number)
71
72
what unit is used to measure a mole and what does the mole unit represent?
mol, the quantity of materials in a sample
73
how many atoms of sodium is in 1 mole?
6.02x10^23 formula units
74
what is molar mass?
mass made of 1 mole (gmol^-1), same as atomic mass
75
how do you find the molar mass of a molecule?
add the masses of the atoms together
76
What do isotopes change?
The physical properties of that element, particularly their half life.
77
what is the equation used to find the number/concentration of moles in a molecule?
n = m/M n=no. of moles m=actual mass M=molar mass
78
what is the no. of moles in 15g of copper?
n= 15/63.546 n=0.236 mol
79
what is relative atomic mass?
the average mass of 1 atom of a molecule/element relative to 1/12th the mass of a carbon-12 atom.
80
How are isotopes written
The elemental symbol (X), with the atomic mass (A)as the superscript (top left) and the Atomic number (Z) written as the subscript (bottom left) A X Z
81
what unit is used when calculating relative atomic mass?
there is no unit for relative atomic mass
82
relative atomic and molar masses are NOT calculated the same way as atomic mass, true or false?
false
83
what is abundance?
refers to the occurrence of an isotope compared to other isotopes of the same element.
84
what is the equation to calculate abundance?
Ar (mass of element) = (% abundance x Ar (of isotope)) + (% abundance x Ar (of isotope))
85
what does % composition show and how is it found?
the fraction of mass of an element in 1 mole of the compound Found by dividing mass of each element present in 1 mole of the compound by the compound's molar mass.
86
How are nanomaterials defined?
Substances that measure less than 100 nanometers across
87
What are three main types of separating mixtures?
Filtration, evaporation and distillation
88
What are physical properties?
Properties that can be observed and measured without changing the substance's chemical identity (e.g. phase, colour, odour, conductivity etc.)
89
What are chemical properties?
Properties that can be observed and measured as a substance's chemical identity changes (E.g. flammability, acidity, reactivity with water etc.)
90
What is an element
A substance that is composed purely of one periodic chemical (E.g. Hydrogen gas, iron, graphite) Are orginised in metals, non-metals and metalloids
91
What is a compound
A substance that is pure composed of one molecule (E.g. water, methane gas)
92
What is a homogenous mixture? 🏳️‍🌈🏳️‍🌈🏳️‍🌈🏳️‍🌈🏳️‍🌈🏳️‍🌈🏳️‍🌈🏳️‍🌈
A mixture between multiple substances that are in the same phase and are uniform in mixture through out. (E.g fruit juice)
93
What is a heterogenous
A mixture between multiple substance that are not uniform in mixture through out and may be in different phase (e.g. Water and oil, water and sand)
94
What is filtration?
The process of moving a heterogenous through a filter which separate smaller particles from larger particles, usually liquid from solid.
95
What is Evaporation?
The process of heating an aqueous homogenous mixture so that the liquid evaporates away, leaving behind the solid.
96
What is simple distillation?
Separating the components of a homogenous mixture of two or more liquids with different boiler points. The component with the lower boiler point boils first, the vapour is then run through a cooling tube and is the condensed liquid is collected in a separate flask.
97
What is filtrate?
The solution that can pass through a filter
98
What is residue?
The solid that remains in the filter
99
What is valency?
How many electrons an atom is gain, lose or share, determined by the element's group.
100
What is Electronegativity
The