Semiconductor Materials and Devices Flashcards
(240 cards)
Give two expressions for the classical kinetic energy of a particle.
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Give the equations for angular frequency and wavevector.
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Give the expression for quantum mechanical KE of a free electron.
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State the TISE.
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Solve the TISE for a free election gas in volume L^3 stating an expression for the quantised energy states.
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State the Bragg reflection condition for electrons incident on crystal planes
n lambda = 2dsin(theta)
How can the Bragg condition be used to define the Brillion zone boundary?
If an electron travels normal to the plane, the Bragg reflection condition occurs when k=nπ/d. This means the electron wave vector will constantly be reflected back and forth (standing wave).
What is the state of the electron energy in a system when the standing waves of electron density has high density overlapping positive ion cores?
Low energy state.
What is the state of the electron energy in a system when the standing waves of electron density has high density between positive ion cores?
High energy state
What is the band gap at the Brillouin zone boundary?
For the same k vector, the electron states have different energies. The difference in these energies is the band gap.
Sketch the extended zone scheme and the reduced zone scheme band structure for electrons in the nearly free electron model.
Check slide 7
Why do energy gaps form at the Brillouin zone boundary in the NFE band structure?
The periodic potential of the crystal lattice causes energy gaps to appear in the FE model.
Define the 1st BZ in terms of reciprocal lattice vectors.
The 1st BZ is a closed volume about the origin in reciprocal space formed by bisecting near neighbour reciprocal lattice vectors.
Sketch band structures for the free electron, NFE, tight binding and free atom with energy on the y axis.
Check slide 9
Derive an expression for density of states.
Check slide 10
Define density of states.
The number of states with an energy between E and E+dE per unit volume.
What is true of the density of states at T=0K
The states are fully occupied up to the Fermi energy, Ef
What distribution defines the occupation of the density of states?
The Fermi-Dirac distribution function.
State the Fermi-Dirac distribution
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State how filled the bands are in a metal.
Electron density is such that the highest occupied band is partially filled.
State how filled the bands are in a semiconductor.
Highest band is completely filled at low T and the difference in energy to the next band is relatively small.
State how filled the bands are in an insulator.
Highest occupied band is completely filled at low T and the difference in energy to the next band is large.
What does conduction require?
A net electron momentum - changing the average k values. This causes a shift of the Fermi surface in k-space.
Why can’t insulators conduct (momentum)?
There are no empty states for the electrons to move into hence the electrons can gain no net momentum.