Sistemi semplici Flashcards

1
Q

What is a simple system in quantum mechanics?

A

A simple system in quantum mechanics is a system for which it is possible to solve the Schrödinger equation explicitly and obtain exact eigenfunctions and eigenvalues.

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2
Q

What is the Schrödinger equation for a free particle?

A

The Schrödinger equation for a free particle is Hψ(x) = -h^2/2m * d^2ψ/dx^2 = Eψ(x).

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3
Q

What are the boundary conditions for the wave function of a free particle?

A

The wave function of a free particle must be finite for all x between -∞ and +∞.

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4
Q

What is the general form of a solution to the Schrödinger equation for a free particle?

A

The general form of a solution to the Schrödinger equation for a free particle is ψ(x) = N * e^(i/h * kx), where N is a normalization constant and k = √(2mE)

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5
Q

What is the condition for the energy of a free particle?

A

The energy of a free particle can take any positive value, as long as it is real.

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6
Q

What is the value of the momentum of a free particle?

A

The momentum of a free particle is p = √(2mE) = k.

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7
Q

What is the probability of finding a free particle between x and x + dx?

A

The probability of finding a free particle between x and x + dx is N^2 * dx, which is independent of x(respects the indetermination)

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8
Q

What is the potential inside and outside the box?

A

he potential inside the box is constant and equal to 0, while outside the box it is infinite.

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9
Q

What are the possible solutions for the Schrödinger equation outside the box?

A

The possible solutions for the Schrödinger equation outside the box are ψ = 0, meaning the probability of finding the particle outside the box is zero.

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10
Q

What is the general solution for the Schrödinger equation inside the box?

A

The general solution for the Schrödinger equation inside the box is f(x) = A cos(kx) + B sin(kx), where k = sqrt(2mE)/h and A and B are constants.

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11
Q

What are the two possible solutions for the wave function inside the box?

A

e two possible solutions for the wave function inside the box are f1 = e^(ikx) and f2 = e^(-ikx), corresponding to waves propagating in the positive and negative x direction, respectively.

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12
Q

What is the most general solution for the wave function inside the box?

A

The most general solution for the wave function inside the box is f(x) = c1e^(ikx) + c2e^(-ikx), where c1 and c2 are constants.

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13
Q

What is the value of B in the normalized wave function?

A

The value of B in the normalized wave function is sqrt(2/a).

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14
Q

What is the energy of the particle inside the box?

A

The energy of the particle inside the box is E_nx = h^2 * n^2/(8ma^2), where n is the quantum number.

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15
Q

What is the form of the wave function for a three-dimensional box?

A

The form of the wave function for a three-dimensional box is ψ(x,y,z) = f(x)g(y)h(z).

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16
Q

What is the energy of the particle in a three-dimensional box?

A

The energy of the particle in a three-dimensional box is E_nxnyz = h^2/8m * (n^2_x/a^2 + n^2_y/b^2 + n^2_z/c^2), where n_x, n_y, and n_z are the quantum numbers.

17
Q

What is the condition for the quantum numbers in a three-dimensional box?

A

The condition for the quantum numbers in a three-dimensional box is n^2 = n^2_x + n^2_y + n^2_z.

18
Q

What’s the degeneracy for energy levels

A

Degeneracy in the context of energy levels refers to the situation where multiple states have the same energy.

19
Q

What are some situations that can be approximated by the particle in a box model?

A

Some situations that can be approximated by the particle in a box model include an electron in a metal, molecules of a gas in a container, and an electron in a conjugated system.