(#) Soil colloids Flashcards

(48 cards)

1
Q

True or false, soil colloids are the most chemically active portion of the soil

A

True

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2
Q

Average soil colloid diameter

A

<1μ or 0.001mm

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3
Q

What are the types of soil colloids?

A

Organic
Inorganic

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4
Q

What are the types of Organic soil colloids?

A

Humus

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5
Q

What are the types of Inorganic soil colloids?

A

Silicate clays
Allophanes
Fe and Al oxides

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6
Q

what is Micelle?

A

a silicate clay crystal

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7
Q

Shape of silicate clays

A
  • flaky, laminated, usually hexagonal
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8
Q

Surface area of silicate clays

A

internal and external

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9
Q

name a silicate clay crystal

A

Micelle

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10
Q

Name silicate clay’s electro negative charges

A

net negatively charged

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11
Q

Types of Silicate clays

A

1:1 (One silica tetrahedon & one aluminum actahedron)
2:1 Expanding type
2:1 Non-expanding type
2:1:1 or 2:2

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12
Q

The type of silicate clay that’s one tetrahedral sheet attached to one side of an octahedral sheet

A

1:1

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13
Q

Name a 1:1 silicate clay

A

Kaolinite

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14
Q

CEC of kaolinite

A

low

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15
Q

True or false, kaolinite has high surface area

A

False

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16
Q

True or false, kaolinite has low water holding capacity

A

True

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17
Q

True or false, kaolinite has low shrink-swell capacity. Why?

A

True, due to strong hydrogen bonding

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18
Q

Which silicate clay has a symmetrical arrangement of two tetrahedral sheets and a central octahedral sheet?

A

2:1 Expanding silicate clay

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19
Q

Name a 2:1 expanding silicate clay

A

Montmorillonite

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20
Q

True or false, montmorillonite has low CEC

21
Q

Montmorillonite is a major component in what kind of soil?

22
Q

What is the D spacing of montmorillonite?

23
Q

True or false, 2:1 Non-expanding silicate clay has the different composition/structure than 2:1 expanding silicate clay

A

false, they have the same composition/structure, it’s just non-expanding doesn’t expand

24
Q

Why do 2:1 non-expanding silicate clays not expand?

A

presence of K+ ions

25
Name a 2:1 Non-expanding silicate clay
muscovite
26
Which silicate clay has two silica tetrahedral sheet and two Mg-dominated octahedral sheet
2:1:1 / 2:2 silicate clay
27
Name a 2:2 silicate clay
chlorites
28
What are the substitutions in a 2:1 silicate clay's tetrahedral sheet
Al^3+ & Si^4+ (negative charge)
29
What does the octahedral interlayer of a chlorite contain?
Mg^2+ & Fe^2+ (positive charge)
30
Hydrous oxide ore are hydrous oxides of Fe and Al commonly dominant in?
Highly weathered soils of tropics and subtropics
31
Name hydrous oxides of Fe and Al
Gibbsite and Goethite
32
True or false, some hydrous oxides of Fe and Al have definite crystaline structure whilst others are amorphus
True
33
True or false, hydrous oxides of Fe and Al are sticky and plastic
false, non-sticky and plastic
34
"short-range order minerals"
allophanes
35
What soil are allophanes prevalent in?
Andisols
36
True or false, Allophanes have low capacity to adsorb cations
false
37
Name two allophanes
allophanes & imogolite
38
What is humus composed of?
C, H, O (non crystaline
39
What are the 3 sources of negative charges?
1) Isomorphous substitution 2) Dissociation of exposed OH groups at the broken edges of the mineral 3) Dissociation of functional groups in organic colloids
40
The source of negative charge wherein centrally coordinated cations are replaced by another cation without alteration of crystal structure of the mineral
Isomorphous substitution
41
In which silicate clay is isomorphous substitution most prevalent?
2:1
42
In which source of negative charge does OH dissociate at a high pH?
Dissociation of exposed OH groups at the broken edges of the mineral
43
In which source of negative charge, when at high pH, creates pH dependent negative charge?
Dissociation of functional groups in organic colloids
44
The interchange between a cation in solution and another cation on the surface of any surface-active material such as clay or organic matter
cation exchange
45
True or false, cation exchange is the result of positive charges in soil colloids, which attract positive ions (cations) from soil solution
False, it's the other way around
46
What is cation exchange capacity (CEC)?
sum of exchangeable cations that a soil can adsorb
47
What is base saturation?
Proportion of CEC that is made up of exchangeable bases
48
The quantity of a substance that exactly reacts with, or is equal to the combining value of, an arbitrarily fixed quantity of another substance in a particular reaction.
Equivalent weight