Soil Surface, Acidity and Nutrients Flashcards

1
Q

What does colloidal material of soil determine?

A

Soil chemistry, nutrients for plant growth and those toxic

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2
Q

Colloids

A

Particles larger than molecules yet small enough to remain microscopic

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3
Q

Why do colloids remain in suspension in liquids?

A

Electrostatic properties and specific surface area

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4
Q

What are electrostatic charged elements of sols?

A

Soil humus, clay minerals

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5
Q

Two groups of silicate clays?

A

1:1 with one lay silica then one Al hydroxide, and 2:1 with two silica layers

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6
Q

What does silica layer ratio determine?

A

Physical properties like shrinking/swelling in response to mooisture and different charge characteristics

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7
Q

How is OM categorised?

A

Humus strictly humic compounds whilst others products of decompostion

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8
Q

What groups compose OM?

A

Hydroxyl, carboxyl, phenol and benzene

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9
Q

What are the divisions of Humus?

A

Fulvic acids
Humic acids

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10
Q

How do humus and clay differ?

A

Size, shape, composition and electrostatic charge

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11
Q

Isomorphic Substituation

A

This is where purity of a substance is impeded by introduction by another element, changing charge imbalance

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12
Q

What structures do silica in clay form?

A

Tetrahedral

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13
Q

Dissasociated hydroxyl in soils…

A

Without dissociation from water…

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14
Q

How doese hydroxyl react in soils?

A

H in OH-R disassociate leaving a negatively charged O-R

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15
Q

How do ions relate to colloids?

A

Decreasing tightness further from the charged surface

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16
Q

Layers of ion cloud of colloids?

A

Innermost stern layer whilst outer diffue layer

17
Q

Cation Exchange Capacity

A

Is the total negative charges within a soil adsorbing plant nutrient cations

18
Q

What does CEC determine?

A

Ability to supply nutrients like K, Ca and Mg

19
Q

What does high CEC mean?

A

High colloidal particle concentration

20
Q

What does CEC measure?

A

Amount of variable and permanent exchange surfaces a soil has

21
Q

Why do anions leach?

22
Q

Wjhat characteristics does soil acidity determine?

A

Variable charge nature, nutrient availability, microbial activity and toxin release

23
Q

How does acidity indicate cations present?

A

Acidic soils have high exchangeable ions like Al, whilst alkaline more Na, Ca and Mg

24
Q

Why is Al toxic?

A

Binds colloids and prevents soil ability to retain base cations, resulting in stunted root development through mitotic inhibition.

25
How can Al be indicated?
Brown stubbly root in upper horizons, inhibiting water uptake, increasing drought suceptibility
26
Types of acidity
Active being total H stock in solution Exchangeable is H and Al within the diffuse layer, moving easily within solution Residual is H and Al locked tightly to colloids
27
Buffering Capacity
This is the ability of soils adjustment to change in ionic composition of soil solution
28
Most important macronutrients?
Nitrogen, Potassium and Phosphorous
29
Nitrogen
5% inorganic, mainly ammonium, nitrate and nitrite, organic material mineralise by microorganisms before avaialble to plants
30
How can Ammonium become available?
Fixation into 2:1 clay mineral structures, where up to 20% of nitrogen can become fixed
31
Why is potassium important?
Disease resistance, photosynthesis, stomatal aperture regulation
32
Importance of phosphorous?
Photosyntehsis, nitrogen fixation, crop growth and root development
33
What does phosphate availability lower with?
Acidic and alkaline conditions through coupling with hydrous oxides of Al and Fe, forming insoluble compounds
34