SPECTROCHEMICAL METHODS Flashcards

(31 cards)

1
Q

Measurements based on light and other forms of electromagnetic radiation

A

Spectrochemical methods

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2
Q

Any analytical method that uses light for measurement of chemical concentrations

A

Spectrophotometry/spectroscopy

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3
Q

Dispersion of light travels through a triangular prism

A

Spectroscopy

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4
Q

Can be thought as a wave or particle

A

Light

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5
Q

Is the distance between crests of a wave

A

Wavelength

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6
Q

Is the number of oscillations per second

A

Frequency

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7
Q

an empirical relationship that relates the absorption of light to the properties of the material through which the light is travelling

A

Beer-lambert’s law

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8
Q

law states that there is a logarithmic dependence between the transmission (or transmissivity), T, of light through a substance and the product of the absorption coefficient of the substance, α, and the distance the light travels through the material

A

Beer-lambert’s law

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9
Q

Plastic ware wherein we will put a sample and light passes through it

A

Cuvette

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10
Q

law states that there is a logarithmic dependence between the transmission (or transmissivity), T, of light through a substance and the product of the absorption coefficient of the substance, α, and the distance the light travels through the material

A

Beer-lambert’s law

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11
Q

fraction of incident light at a specified wavelength that passes through a sample.

A

Transmittance

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12
Q

unitless measure of the transmittance of an optical element for a given length at a given wavelength

A

Optical density

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13
Q

involves interactions of matter with electromagnetic radiation, such as light.

A

Electromagnetic spectroscopy

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14
Q

Electromagnetic specstroscopy can be classified as:

A

Emission spectroscopy
Absorption spectroscopy
Scattering spectroscopy

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15
Q

the study of electromagnetic radiation spectra given off by atoms or molecules that undergo a transition to a lower energy level.

A

Emission spectroscopy

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16
Q

the study of electromagnetic radiation spectra absorbed by atoms or molecules that change energy levels; the atoms usually positioned between a radiation source and the observer

A

Absorption spectroscopy

17
Q

uses the range of the electromagnetic spectra in which a substance absorbs

A

Absorption spectroscopy

18
Q

can be used to determine the concentration of chemical compounds in samples

A

Absorption spectroscopy

19
Q

absorption of infrared radiation,

A

Vibrational spectroscopy

20
Q

is a technique for determining the concentration of a particular metal element in a sample

A

Atomic spectroscopy

21
Q

absorption of infrared radiation

A

Vibrational spectroscopy

22
Q

deals with visible light and shorter wavelengths, since fluorescence is less likely to happen with long wavelengths.

A

Emission spectroscopy

23
Q

absorption of ultraviolet and visible light

A

UV/Visible spectroscopy

24
Q

Measures the absorption of gamma rays by atoms bound in a solid as a function of gamma-ray energy. This is not an analytical technique; it is a means to understand certain microscopic processes in matter

A

Mossbaeur spectroscopy

25
As the quantity of energy (the power) put into the flame is known, and the quantity remaining at the other side (at the detector) can be measured, it is possible, from Beer-Lambert law, to calculate how many of these transitions took place, and thus get a signal that is proportional to the concentration of the element being measure
Atomic absorption spectroscopy
26
is the subset of spectroscopy that deals with the infrared region of the electromagnetic spectrum
Infrared spectroscopy
27
widely used in both research and industry as a simple and reliable technique for measurement, quality control and dynamic measurement.
Infrared spectroscopy
28
As the quantity of energy (the power) put into the flame is known, and the quantity remaining at the other side (at the detector) can be measured, it is possible, from Beer-Lambert law, to calculate how many of these transitions took place, and thus get a signal that is proportional to the concentration of the element being measure
Atomic absorption spectroscopy
29
is the subset of spectroscopy that deals with the infrared region of the electromagnetic spectrum
Infrared spectroscopy
30
It is of special use in forensic analysis in both criminal and civil cases, enabling identification of polymer degradation for example.
Infrared spectroscopy
31
Most widely used method of spectroscopy
Infrared spectroscopy