SPECTROCHEMICAL METHODS Flashcards
(31 cards)
Measurements based on light and other forms of electromagnetic radiation
Spectrochemical methods
Any analytical method that uses light for measurement of chemical concentrations
Spectrophotometry/spectroscopy
Dispersion of light travels through a triangular prism
Spectroscopy
Can be thought as a wave or particle
Light
Is the distance between crests of a wave
Wavelength
Is the number of oscillations per second
Frequency
an empirical relationship that relates the absorption of light to the properties of the material through which the light is travelling
Beer-lambert’s law
law states that there is a logarithmic dependence between the transmission (or transmissivity), T, of light through a substance and the product of the absorption coefficient of the substance, α, and the distance the light travels through the material
Beer-lambert’s law
Plastic ware wherein we will put a sample and light passes through it
Cuvette
law states that there is a logarithmic dependence between the transmission (or transmissivity), T, of light through a substance and the product of the absorption coefficient of the substance, α, and the distance the light travels through the material
Beer-lambert’s law
fraction of incident light at a specified wavelength that passes through a sample.
Transmittance
unitless measure of the transmittance of an optical element for a given length at a given wavelength
Optical density
involves interactions of matter with electromagnetic radiation, such as light.
Electromagnetic spectroscopy
Electromagnetic specstroscopy can be classified as:
Emission spectroscopy
Absorption spectroscopy
Scattering spectroscopy
the study of electromagnetic radiation spectra given off by atoms or molecules that undergo a transition to a lower energy level.
Emission spectroscopy
the study of electromagnetic radiation spectra absorbed by atoms or molecules that change energy levels; the atoms usually positioned between a radiation source and the observer
Absorption spectroscopy
uses the range of the electromagnetic spectra in which a substance absorbs
Absorption spectroscopy
can be used to determine the concentration of chemical compounds in samples
Absorption spectroscopy
absorption of infrared radiation,
Vibrational spectroscopy
is a technique for determining the concentration of a particular metal element in a sample
Atomic spectroscopy
absorption of infrared radiation
Vibrational spectroscopy
deals with visible light and shorter wavelengths, since fluorescence is less likely to happen with long wavelengths.
Emission spectroscopy
absorption of ultraviolet and visible light
UV/Visible spectroscopy
Measures the absorption of gamma rays by atoms bound in a solid as a function of gamma-ray energy. This is not an analytical technique; it is a means to understand certain microscopic processes in matter
Mossbaeur spectroscopy