Stereochem Flashcards

(15 cards)

1
Q

Define diastereomers:

A

stereoisomers that not mirror images of each other

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Define stereoisomers

A

molecules have the same molecular formula, sequence Of bunded atom 1

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Define conformers

A

Molecules that have different spatial arrangement

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Define chiral

A

Carbon molecules that exhibit chirality,contain at least I chiral centre 1

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Define stereogenic

A

An atom within a molecule that, when substituted with different groups, that will

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Define enantiomers

A

Pair of molecules that mirror images each other, does not superimposed

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Define epimers

A

Molecules that have multiple chiral centre

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Define optical activity

A

ability of compound to rotate plane of polarized light

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Define meso

A

Molecule that have chiral centers, but itself achiral

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

key characteristics of meso compound?

A
  1. possess at least 2 chiral centers
  2. internal plane of symmetrical divides molecule
  3. superimposeble on its mirror image
  4. optically inactive
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Define absolute configuration

A

to desccibe 3D arrangements of atoms within chiral molecule

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Cahn-Ingold-Prelog (CIP) Priority Rule based on?

A
  1. Higher atomic number prioritised
  2. Higher mass of isotopes prioritised.
  3. Molecules that have multiple bonds
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Anachiral

A

object superimposeable on its mirror image

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Define atropisomer?

A

a type of stereochemistry isomer

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

define constitutional isomer?

A

Isomers with different atom connectivity

How well did you know this?
1
Not at all
2
3
4
5
Perfectly