Stereochem Flashcards
(15 cards)
Define diastereomers:
stereoisomers that not mirror images of each other
Define stereoisomers
molecules have the same molecular formula, sequence Of bunded atom 1
Define conformers
Molecules that have different spatial arrangement
Define chiral
Carbon molecules that exhibit chirality,contain at least I chiral centre 1
Define stereogenic
An atom within a molecule that, when substituted with different groups, that will
Define enantiomers
Pair of molecules that mirror images each other, does not superimposed
Define epimers
Molecules that have multiple chiral centre
Define optical activity
ability of compound to rotate plane of polarized light
Define meso
Molecule that have chiral centers, but itself achiral
key characteristics of meso compound?
- possess at least 2 chiral centers
- internal plane of symmetrical divides molecule
- superimposeble on its mirror image
- optically inactive
Define absolute configuration
to desccibe 3D arrangements of atoms within chiral molecule
Cahn-Ingold-Prelog (CIP) Priority Rule based on?
- Higher atomic number prioritised
- Higher mass of isotopes prioritised.
- Molecules that have multiple bonds
Anachiral
object superimposeable on its mirror image
Define atropisomer?
a type of stereochemistry isomer
define constitutional isomer?
Isomers with different atom connectivity