structure and properties of materials Flashcards
structural properties of ionic substances
giant ionic lattice structure with a large number of alternating positive and negative ions held together by electrostatic forces of attraction
Hardness of ionic substances
strong forces of attraction between the oppositely charges ions makes ionic compounds resistance to deforming, they are hard but brittle
Melting point and boiling point of ionic substances
a large amount of energy is needed t overcome the strong electrostatic forces of attraction, causing a very high melting point and boiling point
solubility of ionic substances
soluble in water and insoluble in organic solvents
electrical conductivity of ionic substances
when an ionic compound is in the solid state, the ions in the lattice are only able to vibrate about their fixed positions. there are no mobile charge carriers and hence, no electrical conductivity
when an ionic compound is i the aqueous state or molten state, there are mobile charge carriers to conduct electricity and there is electrical conductivity
solubility of simple covalent substances in water
generally insoluble
structure of simple covalent substances
simple covalent structure. small discrete molecules
bonding between simple covalent structures
weak intermolecular forces of attraction
Melting point and boiling point of simple covalent structures
small amount of energy needed to overcome the weak intermolecular forces of attraction. low melting point and boiling point
electrical conductivity of simple covalent structures
consist of electrically neutral molecules with no free electrons or ions. most does not conduct electricity in all states. (except hydrogen chloride with dissolve in water to form mobile ions that can carry charges)
hardness of simple covalent molecules
soft due to the weak intermolecular forces of attraction
structure of giant covalent molecules
giant covalent structure with atoms bonded by covalent bonding
bonding between giant covalent structures
strong covalent bonds between atoms throughout
melting and boiling points in giant covalent structures
very high melting and boiling points as a very high amount of energy is needed to overcome the strong covalent bonds within the atoms
solubility in water for giant covalent substances
insoluble
electrical conductivity in giant covalent structures
does not conduct electricity (except graphite)
each carbon atom in graphite is bonded with three other carbon atoms. the carbon atoms have 1 valence electron that becomes delocalised as it is not used for bonding. there are then delocalised electrons that are mobile and can carry charges within the layers
hardness of giant covalent structures
hard
exception : graphite which has weak intermolecular forces within the layers
structure of macromolecular substances
large polymer-like molecules, small molecules joined together by covalent bonds
bonding between macromolecular structures
strong covalent bonds in a chain or network
mpt and bpt of macromolecular structures
varies depending on molecular weight and structure
typically low mpt and bpt as a small amount of energy is needed to overcome the weak intermolecular forces of attraction between the long chain molecules in the polymer
solubility in water for macromolecular structures
insoluble
electrical conductivity in macromolecular structure
generally does not conduct electricity
hardness in macromolecular structures
varies (some are soft, some are hard)
structure of metallic substances
giant metallic lattice structure. lattice of positive metal ions in a sea of delocalised mobile electrons