Synthetic Routes Flashcards
Conditions and reagents to turn alkene to haloalkane
electrophillic addition, halogen
Conditions + reagents alkene to alkane
Ni cat + Hydrogen , 150°, electrophilic addition (hydrogenation)
Conditions and reagents Alkane to haloalkane
radical sub, halogen, uv light
Conditions and reagents haloalkane to alcohol
NaOH, reflux , nucleophilic sub
Conditions and reagents Alcohol to haloalkane
NaX + H2SO4, reflux , nucleophilic sub
Condition and reagents Alkene to alcohol
Steam + H2SO4 , heat , hydration
Conditions and reagents Alcohol to alkene
Conc H2SO4 , heat , elimination/dehydration
Conditions and reactions Alcohol to keytone
K2Cr2O7 / H+ , reflux , oxidation
Conditions and reactions Alcohol to aldehyde
K2Cr2O7 / H+ , distill , oxidation
Conditions and reactions Alcohol to carboxylic acid
K2Cr2O7 + H+ , reflux , oxidation
haloalkane to nitrile
NaCN, nucleophillic substitution
haloalkane to amine
ethanolic ammonia, nucleo sub
nitrile to carboxylic acid
H2O/HCl
aldehyde to hydroxynitrile
NaCN, H+, nucleo add
alcohol to ester
carboxylic acid, H2SO4
carboxylic acid to ester
alcohol + H2SO4
ester to carboxylic acid
H2O, H+
ester to caroxylate
NaOH
carboxylic acid to acyl chloride
SOCl2, anhydrous
acyl chloride to 1. amide
NH3
u
Acyl chloride to 2. amide
primary amine, rNH2