Synthetic Routes Flashcards

1
Q

Conditions and reagents to turn alkene to haloalkane

A

electrophillic addition, halogen

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2
Q

Conditions + reagents alkene to alkane

A

Ni cat + Hydrogen , 150°, electrophilic addition (hydrogenation)

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3
Q

Conditions and reagents Alkane to haloalkane

A

radical sub, halogen, uv light

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4
Q

Conditions and reagents haloalkane to alcohol

A

NaOH, reflux , nucleophilic sub

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5
Q

Conditions and reagents Alcohol to haloalkane

A

NaX + H2SO4, reflux , nucleophilic sub

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6
Q

Condition and reagents Alkene to alcohol

A

Steam + H2SO4 , heat , hydration

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7
Q

Conditions and reagents Alcohol to alkene

A

Conc H2SO4 , heat , elimination/dehydration

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8
Q

Conditions and reactions Alcohol to keytone

A

K2Cr2O7 / H+ , reflux , oxidation

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9
Q

Conditions and reactions Alcohol to aldehyde

A

K2Cr2O7 / H+ , distill , oxidation

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10
Q

Conditions and reactions Alcohol to carboxylic acid

A

K2Cr2O7 + H+ , reflux , oxidation

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11
Q

haloalkane to nitrile

A

NaCN, nucleophillic substitution

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12
Q

haloalkane to amine

A

ethanolic ammonia, nucleo sub

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13
Q

nitrile to carboxylic acid

A

H2O/HCl

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14
Q

aldehyde to hydroxynitrile

A

NaCN, H+, nucleo add

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15
Q

alcohol to ester

A

carboxylic acid, H2SO4

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16
Q

carboxylic acid to ester

A

alcohol + H2SO4

17
Q

ester to carboxylic acid

18
Q

ester to caroxylate

19
Q

carboxylic acid to acyl chloride

A

SOCl2, anhydrous

20
Q

acyl chloride to 1. amide

21
Q

u

Acyl chloride to 2. amide

A

primary amine, rNH2