Synthetic Routes Flashcards by Mimi Uzoka

Q

Allene → alkane

A

H2 & Ni

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Q

Alkene → haloalkane

A

Hydrogen halide

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Q

Alkane → haloalkane

A

Halogen & UV

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Q

Haloalkane → nitrile

A

CN - & ethanol

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Q

Haloalkane → amine

A

NH3 and ethanol

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Q

Haloalkane→ alcohol

A

Na OH (aq)

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Q

Alcohol to haloalkane

A

Sodium halide & H2 S04

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Q

Alkene → alcohol

A

Hz0 & H3P04

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Q

Alcohol →alkene

A

H2S04 & heat

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Q

Alcohol → Ester

A

Carboxylic acid &H2504 or acid anhydride

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Q

Primary alcohol → carboxylic acid

A

Potassium dichromate & H2S04 & reflux

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Q

Primary alcohol → aldehyde

A

Potassium dichromate & H2SO4 & distillation

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Q

Aldehyde → primary alcohol

A

Na BH4

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Q

Secondary alcohol → ketone

A

Potassium dichromate & H2SO4 & reflux

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Q

Ketone → secondary alcohol

A

Na BH4

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Q

Nitrile → amine

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A

H2 & Ni

Q

Nitrile to carboxylic acid

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A

H2O / HCL & heat

Q

Hydroxynitrile → carboxylic acid

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A

H2O / HCL & heat

Q

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A

Q

Aldehyde → carboxylic acacia

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A

Potassium dichromate & H2SO4 & reflux

Q

Aldehyde →hydrotynitrile

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A

Na CN (aq) & h+ (aq)

Q

Ketone y hydroxynitrile

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A

Na CN (aq) & h+ (aq)

Q

Hydroxynitrile → amine

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A

H2 & Ni

Q

Ester → carboxylic acid

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A

Dilute acid & heat

Carboxylic acid → ester

Alcohol & conc H2504

Ester→ carboxylate

OH- & heat

Acyl chloride → ester

Alcohol

Acyl chloride → carboxylic acid

H2O

Carboxylic acid →acylchloride

SOCI 2

Acylchloride → primary amide

NH3

Acylchloride→2° amide

1° amide