termos

Question 1

Disorder & spontaneous change

Answer 1

S=klnW

Question 2

Entropy & 2nd Law

Answer 2

ΔS=qrev/T

Question 3

Entropy & 2nd Law (differentiated)

Answer 3

dS=dqrev/T

Question 4

Entropy changes of fusion

Answer 4

ΔS=ΔH/Tf

Question 5

Entropy of vaporisation

Answer 5

ΔS=qrev/Tb

Question 6

Entropy and Volume

Answer 6

ΔS=nRln(Vf/Vi)

Question 7

Entropy and Temperature

Answer 7

ΔSm=Cpln(Tf/Ti)

Question 8

Entropy chnages in surroundings

Answer 8

ΔS=-ΔH/T

Question 9

Entropy of recation

Answer 9

ΔS=products-reactants

Question 10

Total Entropy

Answer 10

ΔS=surroudings+system

Question 11

Gibbs free energy

Answer 11

ΔG=ΔH-TΔS

Question 12

Gibbs and spontaneity

Answer 12

ΔG<0

Question 13

Gibbs and pressure

Answer 13

dG=Vdp-SdT

Question 14

Gibbs and pressure 2

Answer 14

G=G+RTln(P/Pstandard)

Question 15

Gibbs and temperature

Answer 15

ΔG=products-reactants

Question 16

ΔG and equillibruin constant k

Answer 16

ΔG=-RTlnk

Question 17

Van’t Hoff Isochore

Answer 17

lnk=-ΔH/R(1/T)+ΔS/R

Question 18

Phase Diagrams

Answer 18

dp/dt=ΔH/TΔV

Question 19

Phase diagrams 2

Answer 19

d(lnp)/dt=ΔH/RT^2

Question 20

Phase diagrams 3

Answer 20

F = C-P+2

Question 21

Lennard-Jones Potential

Answer 21

μ=4ε{(σ/r)^2 - (σ/r)^6}

Question 22

Mixed interactions for size

Answer 22

1/2(σbond1+σbond2)

Question 23

Mixed interactions for well depth

Answer 23

√εbond1 x εbond2

Question 24

Trouton’s rule

Answer 24

ΔSvap=10R

Question 25

Trouton's equation

Answer 25

ΔH/T=ΔS

Question 26

Interactions between ions

Answer 26

V=q1q2/4πεr

Question 27

Interactions between ions mu

Answer 27

μr=μrcosX

Question 28

Decay of van der waals

Answer 28

1/r^6

Question 29

Sum of vdw interactions

Answer 29

V=C/r^6

Question 30

Electric dipole moments

Answer 30

μ=qR

Question 31

Compressability

Answer 31

Z=PV/nRT

Question 32

Mole fractions

Answer 32

x=n1/n1+n2+n3...

Question 33

Kinetic Energy and Temperature relationship

Answer 33

1/2mv^2=3/2kbT

Question 34

Partial pressures

Answer 34

P=nRT/V

Question 35

Ideal Gas Equation

Answer 35

PV=nRT

Question 36

Monoatomic Cpm

Answer 36

3/2R

Question 37

Monoatomic Cpm

Answer 37

5/2R

Question 38

Latimer diagrams

Answer 38

ΔGcell = -nFEcell

Question 39

Latimer n

Answer 39

no. of e- transferred

Question 40

Latimer F

Answer 40

Faraday Constant

Question 41

Latimer E

Answer 41

Cell potential

Question 42

Nernst Equation

Answer 42

E = E -RT/nF lnQ

Question 43

Frost diagrams

Answer 43

dE/dpH=-m/n(0.059vpH) GRADIENT

Question 44

Cell electric

Answer 44

Ecell=Cathode-Anode

Question 45

Overpotential in batteries

Answer 45

Ecell=cathode-anode-overpotential