Terpenes Flashcards

1
Q

What are Terpenes

A

They are important class of compounds which typically consist of 5 Carbons multplets.

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2
Q

What are Terpenoids

A

Terpenes by with other functional groups in this, eg Oxygen

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3
Q

Examples of a Terpene and terpenoid and draw it

A

geranyl and Genraniol

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4
Q

what are two important biosynthesis pathways

A

Mevalonate and deoxyxylulose phosphate pathways

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5
Q

importance of the mevalonate pathway. draw it

A

draw this pathway to practice
starts with acetyl-CoA

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6
Q

importance of the deoxyxylulose phosphate pathway. draw it

A

draw this pathway satarts with compound from pyruvic aci

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7
Q

higher plants use which pathway

A

these plants use both pathways

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8
Q

The mevalonate pathway of higher plants are used to product?

A

sterols, some sespuiterpnes and ubiquinones

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9
Q

what is the enzyme that causes the catalysation of acetoacetyl-Coa in the first step of the mevalonate pathway

A

acetoacetyl-Coa Thiolase

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10
Q

acetyl-Coa and acetoacetyl-Coa condestation results in what by catalysation by what

A

3-Hydroxy-3MethylGlutary-Coa (HMG-CoA) and catalysed by HMG-Coa Synathsase.

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11
Q

what enzyme catalyses the reductive conversion of HMG-Coa to __ _ _ _ _

A

3-Hydroxy-3MethylGlutaryl-Coa (HMG-CoA) reductatse catalyses the reductive conversion of HMG-CoA to mevalonic acid.

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12
Q

How is Mevalonic Acid (MVA) converted to MVA 5-diphosphate

A

by use of mevalonate kinase and phosphomevalonate kinase

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13
Q

what is MVA 5-Diphospahte converted to by what enzyme

A

Converted to IPP by phosphomevalonate kinase. IPP then can be converted to DMAPP by isomerisation

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14
Q

what is the MEP pathway

A

it is the 2-C-methyl-D-erythritol 4-phosphate (MEP) pathway.
deoxyxylulse phosphate pathway and the non-mevalonate pathway

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15
Q

what are IPP adn DMAPP used to produce

A

prenyl side chains and plastoquinones.
as well as hemi, mono, sesqui, di, and tetraterpenes

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16
Q

what is a pinacol-type rearrangement

A

conversion of a 1,2-diol to a carbonyl compound under acidic conditions.
an alkyl group from the adjacent carbon migrates to the carbonation center

17
Q

what are all terpenes formed from and example of first terpene

A

IPP and DMAPP as well as geranyl PP

18
Q

how are cyclic terpenes formed

A

from the carbcation cyclysation by an enzyme

19
Q

examples of cyclic terpenes and their seven types

A

menthol
Methane. Pinane, Bornane, Fenchane, Isocamphane, Carana, Thujane

20
Q

what is menthol and its structure

A

it is a terpene

21
Q

application of these compounds

A

scents, food, medicinal - antiseptic, antiflammatory, antihypertensive, cholesterol reduction industrial

22
Q

what are essential oils

A

they are volatile oils, majority but not all are terpenes/oids. Monoterpenes, sesquiterpenes and diterpenes,

23
Q

essential oil role in nature

A

protection, attractants and allelopathy

24
Q

example of the only hemiterpene and example of hemiterpeniod

A

isoprene
prenol

25
Q

features of the monoterpenes

A

floral odour and unstable

26
Q

feature of acyclic monoterpenoids draw example

A

more stable than monoterpenes
geraniol (draw it)

27
Q

cyclic monoterpenes

A

ring structure
limonene
good solvent for glue

28
Q

bicylic monoterpene draw

A

pinene (draw)

29
Q

farnesene and humulene are what type of terpene

A

sesquiterpenes

30
Q

Importance of Triterpenes

A

the linear is squalene and the cyclic is sterol

31
Q

examples of plant steroids

A

Beta-Sitosterol - plant sterol with cholesterol reduction properties
brassinosteroid - canola

32
Q

examples of animal steroids

A

Cholesterol
Hormones such as Androgens and Estrogen

33
Q

cardiac glycosides

A

treat congestive heart failure and cardiac arrhythmia - example of diterpenes with digitoxin

34
Q

Tetraterpenes

A

Plant pigements
carotenes and carotenoids
photosynthesis and antioxidants