Test 1 Flashcards

(47 cards)

1
Q

oxidation

A

loss of electrons, addition of oxygen or removal of hydrogen

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2
Q

reduction

A

gain of electrons, removal of oxygen or addition of hydrogen

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3
Q

epoxide

A

unstable system, typically polymerizes rapidly and easily, it is used to make something waterproof

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4
Q

what will make an epoxide

A

peracid with any alkene

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5
Q

cold vs hot in reactions

A

cold gives the oxidizing agent less reactivity which slows it down, limits the reagent making it less reactive, will control the reaction better

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6
Q

syn addition

A

adds across double bonds to same side at the same time

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7
Q

what are aldehydes oxidized to

A

carboxylic acids

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8
Q

what does heat do to a reaction

A

gives it energy to be more reactive, splits the double and triple bonds to form aldehydes

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9
Q

What does a ketone get oxidized to

A

nothing, it cannot be oxidized any further

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10
Q

ozoloysis

A

type of oxidatice cleavgae that uses ozone to add an oxygen to both sides making aldehydes

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11
Q

degrees of saturation in an alkene

A

1

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12
Q

degrees of saturation per ring

A

1

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13
Q

degrees of unsaturation in an alkyne

A

2

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14
Q

1 unit

A

monomer

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15
Q

2 units

A

dimer

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16
Q

3 units

A

trimer

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17
Q

4 units

A

tetramer

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18
Q

5 units

A

pentamer

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19
Q

6-11 units

20
Q

12 units and greater

21
Q

examples of types of polymers

22
Q

radical

A

single electron, very unstable, very reactive

23
Q

what is an alcohol

A

alkyl group attached to a hydroxide

24
Q

what forces does an alcohol use

A

hydrogen bonds

25
what forces does an ether use
dispersion forces
26
is water an acid or a base
both, it depends on what it is reacting with
27
large ka
strong acid
28
small Ka
weak acid
29
large pKa
weak acid
30
small pKa
strong acid
31
how does markovnikov reaction add hydorgen
to the carbon with the most hydrogens
32
what is syn addition
adds to the same side at the same time
33
what is a primary alcohol oxidized to?
aldehyde and then a carboxylic acid
34
what is a secondary alcohol reduced to
ketone
35
what is a tertiary alcohol reduced to?
nothing
36
how is a carboxylic acid reduced?
aldehyde--> primary alcohol or ketone --> secondary alcohol
37
IR of an Alkane
4 peaks 2 at 28 and 2900 CH 1 at 1470 CH2 1 at 1360 CH3
38
IR of an aromatic compound
4 small peaks | 1600-2000
39
IR of an alkyne
C triple bond C seen at 21-2200 | terminal hydrogen at 3300
40
IR of an alcohol
32-3600 | strong and broad (smoother peak)
41
IR of an amine
peaks between 32-3600 | 2 peaks if 2 hydrogens, 1 peak if 1 hydrogen
42
IR of a ketone
C=O at 1650-1750
43
IR of an aldehyde
29 and 2700
44
IR of a carboxylic acid
hydroxide group at 25-3600 very broad curve something around 1700
45
IR of an Ester
11-1200 C-O | 16501750 C=O
46
IR of an Ether
11-1200 C-O | Don't see the carbonyl peak
47
IR of a Nitrile
C triple bond N 21-2200