TEST 1 Flashcards

1
Q

electron orbital procession

A

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2…….

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2
Q

Electron Configuration for Calcium (Ca)

A

1s2 2s2 2p6 3s2 3p6 4s2 OR [Ar] 4s2

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3
Q

Electron configuration for Iron (Fe)

A

1s2 2s2 2p6 3s2 3p6 4s2 3d6 OR [Ar] 4s2 3d6

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4
Q

Electron configuration for Silicone (Si)

A

1s2 2s2 2p6 3s2 3p2 OR [Ne] 3s2 3p2

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5
Q

Cation

A

positively charged
lost electron

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6
Q

Most electronegative atom and Charge number

A

Flourine= 4.0

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7
Q

Ionic bond electronegativity & ex

A

> 1.9
Na-O

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8
Q

Polar bond electronegativity & ex

A

.5-1.9
C-O
C-N
C-F

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9
Q

Nonpolar Covalent Bond electronegativity & ex

A

<.5
C-H
C-C

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10
Q

Carbocation

A

3 valence electrons
no lone pairs

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11
Q

Carboanion

A

5 valence electrons
1 lone pair

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12
Q

best center atom of a molecule?

A

the one that can form most bonds

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13
Q

What to do with total valence electrons in a molecule?

A

find total number of VE’s, the find if its divisible by 8. If it is there are no lone pairs on central atom. If it isn’t then find the closest number that is divisible by 8 and subtract the total VE’s by the closest number. That number is the number of electrons on central atom.

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14
Q

ammonium

A

nitrogen with 1 less electron

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15
Q

amine

A

nitrogen with 5 Ve’s

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16
Q

anionic amine

A

nitrogen with an extra e

17
Q

oxonium

A

oxygen with 1 less Ve

18
Q

oxo

A

oxygen with 6 Ve’s

19
Q

oxide

A

oxygen with 1 extra Ve

20
Q

stronger bond between sigma & pi

A

sigma>pi

21
Q

pi bond constitution

A

overlapping of sideways p orbitals over a sigma bond

22
Q

things to avoid in lewis structures

A

0-0
0-halogens (flourine column)
tri-cyclic rings

23
Q

Shape that will occur generally from Sp orbital

A

linear
180

24
Q

Shape that will occur generally from Sp2 orbital

A

trigonal planar
120

25
Q

Shape/bond angle that will occur generally from Sp3 orbital

A

tetrahedral
109.5

26
Q

variations of SP2 orbital shape

A

linear like (2 lone pairs)
bent (planar, one pair of lone electrons)

27
Q

variations of sp3 orbital

A

bent (planar 2 pairs of lone electrons)
pyramindal( 1 pair of lone electrons)

28
Q

likely hydrogen bonds & examples

A

H-N
H-O
H-S
H-any halogen

NH3 H20 CH3OH CH3NH2 CH3CO2H

29
Q

lewis base

A

electron PAIR donor
nucleophile

30
Q

lewis acid

A

electron PAIR acceptor
electrophile

31
Q

water pka and conjugate base

A

15.7 pka
OH-