TEST 2 Flashcards
1
Q
Cr containing compounds function
A
oxidizer
2
Q
KMnO4
A
oxidizer
3
Q
LiAlH4
A
strong reducer
4
Q
Class 1 carbonyls
A
carbonyls with no leaving group/electronegative atom
5
Q
Class 2 carbonyls
A
carbonyls with a LG/electronegative atom
6
Q
oxidation
A
decreases H-C bonds
7
Q
reduction
A
increases H-C bonds
racemic product
8
Q
aldehydes reduce to
A
primary alcohols
9
Q
ketones reduce to
A
secondary alcohols
10
Q
carboxylic acids reduce to
A
aldehydes then primary alcohols
11
Q
metal hydrides
A
LiAlH4 or NaBH4
reduce selectively-usually only carbonyls
12
Q
hydrogenation
A
reduces selectively-alkenes first then carbonyls if in excess
13
Q
DIBAL-H
A
reduces, but usually only once
14
Q
LiAlH-tri tertbutoxy
A
reduces, but usually only once
15
Q
A
