Test 3 Flashcards
(52 cards)
how can you tell valence electrons from the periodic table?
group
how can you tell the number of shells from the periodic table?
period
Orbitals and orientations (there can be two electrons in each orientation)
Spherical - 1
Peripheral - 3
Diffuse - 5
Fundamental - 7
Orbital
- also known as an orientation
- a “pocket” within the subshell that can hold up to 2 electrons of different spin
Aufbau Principle
At ground state, electrons must have the lowest possible energies
Pauli exclusion principle
If n, l, and ml are the same for two electrons, they must have different ms (or spin)
-If a box already has an arrow, the second arrow must point in the opposite direction.
Hund’s rule
- orbitals within a subshell have equivalent energy, and since electrons repel, they spread out through out the orbitals as much as possible
- Because electrons repel each other, they spread out until they no longer can
how many orbitals and electrons can fit in the s subshell?
1-2
how many orbitals and electrons can fit in the p subshell?
3-6
how many orbitals and electrons can fit in the d subshell?
5-10
how many orbitals and electrons can fit in the f subshell?
7-14
principle quantum number
- n
- the number of shells
- n = 1,2,3 etc..
angular momentum quantum number
- l
- The subshell
- l = 0,1,2,3 for s, p, d, and f respectively
magnetic quantum number
- ml
- tells the orbital
- 1,0 +1
slit screen experiment
-showed that electrons must be spinning because sometimes they are attracted to the magnet. Whether an electron has an up or down spin is completely random. IF one electron in an orientation changes, the other must change as well.
spin quantum number
- ms
- ms = +1/2 up
- ms = -1/2down
- when something is spinning and it hits something, its spin will determine whether it deflects to the right or to the left
paramagnetism
a weak attraction to a magnetic field
-occurs when there are one or more unpaired electrons
diamagnetism
- weak repulsion from a magnetic field
- occurs when all electrons are paired
two forms of stability
- having the lowest possible energy
- having exactly filled or half-filled subshells
however, having lowest possible energy in order to be stable breaks down in the transition metals because….
sometimes, an electron will move up a level (breaking the principle) to further stabilize an atom by having either a filled or half-filled subshell for the valence electrons
levels of stability (even charge distribution leads to the most stability
- most stable: full s and p
- stable: full subshells in general
- medium stable: exactly half-filled subshells
- not particularly stable: anything else
transition metals
- have incompletely filled d subshells, and will readily lose electrons to try to stabilize
- Form cations (although they will not be quite isoelectronic with a noble has, they will have full s and p subshells like a noble gas
ionic reaction
any time something loses/gains electrons
-happens because every participating atom either loses or gains electrons ignored to become isoelectronic with a noble gas
atomic radius
- increases diagonally from the top right to the bottom left (protons decrease to the left and shells increase toward the bottom)
- Increases in the same pattern as shielding because shielding lessens the nucleus’s ability to hold on to its electrons
- distance from the nucleus to the valence shell (measured as 1/2 the distance between two nuclei that are bonded together