The Photoelectric Effect Flashcards

1
Q

threshold frequency

A

The lowest frequency of light that when shone on a metal will cause electrons to be released from it, ( by the photoelectric effect )

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2
Q

work function

A

The minimum amount of energy required for an electron to escape a metals surface

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3
Q

Equation with work function and threshold frequency

A

fo = Φ / h

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4
Q

Max Plancks wave packets

A

Max Planck was the first person to suggest that EM waves can only be released in discrete packets, or quanta
E = hf = hc / λ
E = Energy of one wave-packet in J

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5
Q

Max kinetic energy equation

A

hf = Φ + Ekmax
or Ekmax = Φ + 0.5mvmax squared

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6
Q

What is the photoelectric effect?

A

If you shine radiation of a high enough frequency onto a surface of metal, it will instantly admit electrons.
For most metals, the necessary frequency falls in the ultraviolet range
Because of the way atoms are bonded together and metals, metals contain electrons that are able to move about the metal
The free electrons on or near the surface of the metal absorb energy from radiation making them vibrate
Electron absorbs enough energy the bond holding it to the metal can break and the electron can be released. This is called the photoelectric effect and the electrons admitted are called photoelectrons.

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7
Q

Main conclusions to the photoelectric effect:

A

-For a given metal no photo electrons are emitted if the radiation has a frequency below a certain value - this is called a threshold frequency
-Electrons are emitted with a variety of kinetic energies ranging from 0 to maximum value. This value of maximum kinetic energy increases with the frequency of radiation.
-The intensity of radiation amount of energy energy per second hitting an area of the metal the maximum kinetic energy of the photo electrons is unaffected by the varying intensity of the radiation
-The number of electrons admitted per second is proportional to the intensity of the radiation

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8
Q

Kinetic energy of photo electrons

A

The higher the intensity of the wave the more energy should transfer to each electron-the kinetic energy of the electrons should increase with intensity
Theory can’t explain the fact that the kinetic energy depends on the frequency in the photo Electric effect

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9
Q

Einstein’s photons

A

Sign went further by suggesting that electromagnetic waves and the energy they carry can only exist in discrete packets. He calls these wave packets photons
He saw these photos of lights as having one and one, particle-like interaction with an electron in a metal surface
Each photon would transfer all its energy to one specific electron
The photon model could be used to explain the photo electric effect

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10
Q

Demonstrating the photo Electric effect

A

The photo Electric effect can be demonstrated with a simple experiment
Zinc plate is attached the top of an electroscope (which is a box containing a piece of metal with a strip of gold leaf attached)
The zinc plate is negatively charged (which means the metal in the box is negatively charged). The negatively charged metal the gold leaf, causing it to rise up.
UV light is then shone onto the zinc plate
The energy of the light causes electrons to be lost from the zinc plates via the photoelectric effect.
As the sink plates and the metal lose their negative charge the gold leaf is no longer repelled and so falls back down

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11
Q

Stopping potential

A

The maximum kinetic energy can be measured using the idea of stopping potential
Photo electrons admitted by the photo electric effect can be made to lose energy by doing work against an applied to potential difference
The stopping potential is the potential difference needed to stop the fastest moving electrons travelled it with kinetic energy
The work done by the potential difference in stopping the fastest electrons is equal to the energy they were carrying
eVs = Ek(max)
e = 1.6x10-19
Vs = stopping potential

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12
Q

The electron volt

A

The kinetic energy carried by an electron after it’s been at accelerated from rest through a potential difference of one volt
The energy gained by an electron (eV) is equal to the accelerating voltage(V)
1eV = 1.6x10^-19

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13
Q

Excitation

A

The movement of an electron to a higher energy level in an atom

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14
Q

Ground state

A

The lowest energy level of an atom or the lowest energy level for an electron in an atom

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15
Q

Discrete energy levels in an atom

A

Electrons in an atom can only exist in certain well-defined energy levels
Each level is given a number , with N=1 representing the low energy level and electron can be, the ground state
We say that’s an electron is when it’s in an energy level higher than the ground state

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16
Q

Electrons moving up and down an energy level

A

Elections can move down and then energy level by a photon
Since these transitions are between definite energy levels, the energy of each photon emitted can only take a certain value

17
Q

Electron transitions

A

The energy carried by a photon emitted after a transition is equal to the difference in energies between the two levels of the transition
Electrons can also move energy levels if they absorb a photon with the exact energy difference between the two levels
The movement of an electron to a higher energy level is called excitation

18
Q

Ionisation

A

When an electron has been removed from an atom, the atom is ionised
The energy of each energy level within an atom or shows the amount of energy needed to remove the electron from that level

19
Q

The ionisation energy

A

The ionisation energy of an atom is the amount of energy needed to remove an electron from the ground state atom

20
Q

Photon emission-fluorescent tubes

A

Fluorescent tubes use the excitation of electrons and photon emission to produce visible light
They contain mercury vapour which a high voltage is applied
The high voltage accelerates fast moving electrons that ionised some of the mercury atoms producing more free electrons
When this flow of electrons collides with the electrons in the mercury atoms The atomic mercury electrons are to higher energy level
When these electrons return to their ground states they lose energy by emitting high energy photons in the UV range
The photons admitted have a range of energies and wavelengths that correspond to the different transitions of the electrons
Coating on the inside of the tube absorbs these protons electrons to a much higher energy level
These electrons, then cascade down the energy levels and lose energy by many lower energy photons of visible light

21
Q

Line emission spectrum

A

Seen as a series of bright lines against the black background, each line corresponding to a particular wavelength of light emitting by the source
Spectrum provides evidence that the electrons in the atoms exist in discrete energy levels. Atoms can only admit photons of energies equal to the difference between two energy levels.
Since only certain photon energies are allowed, only see the corresponding wavelengths in the line spectrum

22
Q

Getting a line spectrum

A

If you split the lights from the fluorescent tube with a prism or a diffraction grating you get a line spectrum
Diffraction gratings prisms of different wavelength at different angles
The fraction grating produces much clearer and More defined spectral lines than the prism

23
Q

Line absorption Spectra
Continuous spectra

A

The spectrum of white light is continuous
If you split the light up with a prism, the colours all merge into each other
There aren’t any gaps in the spectrum
Hot things admit a continuous spectrum in the visible and infrared
All the wavelengths are allowed because the electrons are not confined to energy levels in the object producing the continuous spectrum
The electrons are not bound to atoms and are free

24
Q

What are line absorption spectra?

A

When light with a continuous spectrum of energy(white light) passes for a cool gas.
At Low temperatures most of the electrons in the gas atoms will be in their ground states
Photons of the correct wavelength are absorbed by the electrons to excite them to higher energy levels
These are missing from the continuous spectrum when it comes out the other side of the gas
You can see a continuous spectrum with black lines corresponding to the absorbed wavelengths

25
Q

Comparing line absorption, spectra and emission spectra

A

If you compare the absorption and emission spectrum of a particular gas the black lines in the absorption spectrum match up to the bright lines in the emission spectrum

26
Q

Diffraction

A

When a beam of light passes through a narrow gap, it spreads out
This is called diffraction
Diffraction can only be explained using waves
If the light was acting as a particle particle in the beam would either not get through the gap(if they were too big), or just straight and the beam would be unchanged

27
Q

The photo electric effect

A

The results of photo Electric effect experiments can only be explained by thinking of light as a series of particle like photons
If photon of light is a discrete bundle of energy and it can interact with an electron in a one-to-one way
All the energy in the photon is given to one electron

28
Q

Wave particle duality

A

The photoelectric effect and diffraction show that light behaves as both particle and wave
This is an example of a phenomenon known as wave particle duality

29
Q

De broglie equation

A

Lambda = h/mv
Lambda = de Broglie wavelength(m)
M = mass in KG
V = velocity
h = plancks constant

30
Q

Electron microscopes

A

A shorter wavelength gives smaller diffraction effects
This fact is used in the electron microscope
Diffraction effect blur detail on an image
If you want to resolve tiny detail on an image, you need a shorter wavelength
Light blur out detail more than electron waves so an electron microscope can resolve final detail than a light microscope
They can let you look at things as tiny as a single strand of DNA