The rate and extent of chemical change-paper 2 Flashcards

1
Q

What is the rate of chemical reaction?
One slow and fast reaction?

A

1)how fast the reactants are changed into products.
2)slowest is the: rusting of iron, Burning=fast reaction

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2
Q

1)Speed of reaction is?
2)Steeper the line means, when does the line become flat?
3)What does the quickest reaction mean?

A

1)recording the amount of product formed amount of reactant used up over time.
2)steeper the line= faster rate reaction. line less steep as reactants are used up.
3)quickest reactions=steepest lines, flat in the least time.

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3
Q

The rate of a chemical reaction depends on WHAT AND WHY?
Explain the activation energy?

A

WHAT:
collision frequency of reacting particles more collision=faster the reaction is.
WHY:
energy transferred during a collision. Particles collide enough energy collision to be successful.
ACTIVATION ENERGY:
minimum amount of energy that particles need to react break bonds in the reactant

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4
Q

The Rate of Reaction Depends on Four Things?

A

1) Temperature.
2) concentration solution/pressure of gas.
3) Surface area
4) presence of a catalyst.

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5
Q

How does Increasing the Temperature Increases the Rate? 3

A

1)temperature is increased=particles all move faster.
2)collide more frequently= more energy collisions/sucessful ones
3)enough energy to make the reaction happen= activation energy

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6
Q

How does Increasing the Concentration or Pressure Increases the Rate? 3

A

1)concentrated, more particles knocking about same volume.
2)pressure of a gas is increased=same number particles occupies smaller space.
3)collisions between the reactant particles more frequent.

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7
Q

How does Increasing the Surface Area Increases the Rate?

A

1)reactants is a solid, breaking it up into smaller pieces increase SA:V
2)same volume of the solid, particles around it have more area=collisions more frequently.

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8
Q

How does Using a Catalyst Increases the Rate?

A

1)speeds up a reaction, without being used up in the reaction itself.
2)decreasing activation energy needed reaction to occur. providing an alternative reaction pathway with a lower activation energy.

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9
Q

1)Measure the Rate of a Reaction and the equation?
2)Units for gas, solid, time?
Equation for rate of reaction?

A

1)observed how quickly the reactants are used up, how quickly products formed:
2)product/ reactant gas measure amount in cm3 .solid= grams (g). Time seconds (s).

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10
Q

What are the 2 ways to record Precipitation and Colour Change?
What are the 2 negative?

A

1)record the visual change in a reaction
2)observe a mark through the solution long it takes disappear

-subjective
-can’t plot a rate of reaction graph from the results.

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11
Q

1 method Change in Mass (Usually Gas Given Off), a negative and a positive?

A

1) produces a gas mass balance. Gas released, mass disappearing measured on the balance.
2)quicker reading balance drops, faster reaction= measurements regular intervals, plot graph=find rate.

-accurate
-releasing gas into the room.

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12
Q

1 method Volume of Gas Given Off, 1 negative 1 positive?

A

1) gas syringe measure volume gas given =more gas given off during a time faster
2)regular intervals, plot graph

.volumes accurate nearest cm
-reaction too vigorous, blow plunger out

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13
Q

How to Magnesium and HCI React to Produce H, Gas METHOD 5 and RESULT 1?

A

1) 50cm3 dilute hydrochloric acid conical flask with a gas syringe and a plug
2) add magnesium ribbon to the acid start stopwatch
3) Every 10 seconds, record the volume of gas produced.
4) Plot the results in a table
5) Repeat more concentrated acid solutions.
higher conc=faster rate of reaction

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14
Q

How to Sodium Thiosulfate and HCL Produce a Cloudy Precipitate METHOD? 5

A

1) temperature: 20
50 cm3 dilute sodium thiosulfate to a conical flask.
2) Place flask piece of paper black cross drawn on it.
3)Add 10 cm3 dilute HCI to flask, start stopwatch and record temperature
4) cross disappear through cloudy sulfur, time how long it takes to go.
5) repeated solutions reactant at different starting temperatures

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15
Q

How to Calculate the Mean Reaction Rate from a Graph? 2

A

1) rate reaction graph= amount product formed amount reactant used y-axis, time on the x-axis.
2) mean rate whole reaction= overall change in the y-value divide total time taken for reaction.

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16
Q

How to find Reaction Rate at a Particular Point? 2

A

1)draw a tangent to the curve - a straight line that touches the curve at one point and doesn’t cross it.
2) Gradient= change in y/change in x)

17
Q

Why will Reversible Reactions Reach Equilibrium+process? 5

A

1)reactants react, concentrations fall forward reaction slow down.
2)more products made concentrations rise, backward reaction will speed up.
3) forward reaction same rate as backward one =equilibrium
4)reversible reaction in a ‘closed system’. none escape and nothing can get in.

18
Q

What is a dynamic equilibrium? 2

A

1.both reactions still happening, no overall effect.
2.concentrations reactants and products reached balance won’t change.

19
Q

What does the position of equilibrium depend on? 3

A

.temperature
.pressure (only gases).
.concentration of the reactants and products

20
Q

Can Reversible Reactions Be Endothermic and Exothermic (thermal decomposition)? 2

A

1) reversible reactions=reaction endothermic one direction, exothermic other
2) energy transferred from surroundings endothermic reaction=energy transferred to surroundings in exothermic reaction= Thermal decomposition.

21
Q

What is le Chateliers principle?
What is it used for?

A

1) Le Chatelier’s Principle= change conditions reversible reaction at equilibrium, counteract that change.
2) used predict the effect of any changes you make to a reaction system.

22
Q

Changes to the Temperature and how does equilibrium respond? 2

A

1) decrease temperature=equilibrium move exothermic direction produce more heat + reactant or product
2) raise temperature=equilibrium move in endothermic direction to try to decrease it.

23
Q

Changes to the Pressure and how does equilibrium respond, how do you know which side has more? 3 (gases)

A

1) increase pressure, equilibrium reduce it move direction fewer molecules of gas.
2) decrease the pressure, equilibrium increase it move direction of more molecules of gas.

-balanced symbol equation see which side more molecules of gas

24
Q

Changes to Concentration and how does equilibrium respond? 3

A

1) change concentration= not equilibrium.
2) increase concentration reactants decrease it by making more products.
3) decrease the concentration of products increase it by reducing amount reactants.

25
Q

Why can the Position of Equilibrium Can be on the Right or the Left? 2

A

1)reaction’s equilibrium amounts of reactants and products not equal.
2) equilibrium lies to the right= concentration of products is greater than that of the reactants

26
Q

Temperature water boils at?

A

100c