thee shalt not forget Flashcards

thou shalt not forget (57 cards)

1
Q

What is the difference between separating compounds and mixtures?

A

Compounds can be separated into elements by chemical changes, and mixtures can be separated by physical changes.

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2
Q

How does filtering separate mixtures?

A

Filtering separates mixtures based on differences in particle size.

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3
Q

What is distillation used for?

A

Distillation separates mixtures based on differences in boiling point.

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4
Q

What principle does chromatography rely on?

A

Chromatography separates mixtures based on differences in polarity.

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5
Q

In paper chromatography, which component moves up the farthest?

A

The component that is most similar in polarity to the ‘mobile phase’.

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6
Q

What is the law of conservation of mass?

A

Mass is conserved during chemical and physical changes.

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7
Q

How can you estimate the volume of a liquid in a container?

A

Read in between the graduated markings for one more significant figure.

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8
Q

What is the ranking of measuring devices from least precise to most precise?

A

Beaker, graduated cylinder, volumetric flasks, burette.

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9
Q

What is the formula for density?

A

Density = mass/volume.

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10
Q

Does the % composition by mass of a pure compound change?

A

No, it does not change.

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11
Q

What happens to an electron in a higher energy level?

A

It is farther away from the nucleus and has less Coulombic attraction, making it easier to remove.

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12
Q

What happens to ionization energy as you move across a row on the periodic table?

A

Ionization energy increases due to increased Zeff, which attracts valence electrons more strongly.

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13
Q

What does a PES graph indicate about electron sublevels?

A

The higher the peak, the more electrons there are in that sublevel.

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14
Q

How do you write the electron configuration for a cation?

A

Remove valence electrons first, then d-orbital electrons if necessary.

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15
Q

What are isotopes?

A

Isotopes of an element have the same number of protons but different numbers of neutrons.

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16
Q

What do mass spectroscopy graphs measure?

A

They measure atomic masses of isotopes.

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17
Q

What do elements in the same group have in common?

A

They have similar chemical and physical properties.

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18
Q

How do cations and anions compare in size to their neutral atoms?

A

Cations are smaller and anions are larger than their atoms.

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19
Q

What type of bond is formed between two nonmetals?

A

Covalent bonds.

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20
Q

How are ionic bonds formed?

A

When a metal transfers electrons to a nonmetal, and the opposite charges attract.

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21
Q

What do combustion reactions produce?

A

CO2 and H2O.

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22
Q

What is the empirical formula rhyme?

A

% to mass, mass to mole, divide by small, times until whole.

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23
Q

What is the relationship between the molecular formula and the empirical formula?

A

The molecular formula is a whole number multiple of the empirical formula ratio.

24
Q

How do you calculate % yield?

A

% yield = (experimental/theoretical).

25
What determines the amount of product in a reaction?
The limiting reactant.
26
Why are gas mixtures homogeneous?
Due to the constant random motion of the particles.
27
What causes gas pressure?
Collisions of particles with the walls of the container.
28
What is the relationship between pressure and volume?
P and V are inversely related.
29
What is the gas law equation?
PV=nRT.
30
What is the volume of one mole of an ideal gas at STP?
22.4 Liters.
31
What is the relationship between gas pressure and the number of moles?
They are directly related.
32
What is the formula for molar mass in terms of gas properties?
Molar Mass = dRT/P.
33
What does temperature represent in terms of gas behavior?
Average kinetic energy.
34
What is the relationship when collecting gas by water displacement?
Ptotal = Pdry gas + Pwater vapor.
35
When do real gases behave most like ideal gases?
At high temperature and low pressure.
36
What characterizes exothermic reactions?
(−) ΔH; heat is a product.
37
What does ΔHrxn represent?
Bonds broken − Bonds formed.
38
What happens to ΔH when a reaction is reversed?
The sign for ΔH changes.
39
What is the bond angle for a molecule with 4 domains?
109.5°.
40
What is the hybridization for 3 domains?
sp2.
41
What is the significance of lattice energy?
It is the energy to break an ionic bond in a compound.
42
What is the difference between interstitial and substitutional alloys?
Interstitial alloys have smaller atoms fitting between larger atoms, while substitutional alloys have similar-sized atoms replacing each other.
43
What is required for a reaction to occur?
Particles must collide at the correct orientation and with a minimum energy (activation energy).
44
How can you speed up a reaction?
Add a catalyst, increase reactant concentration, increase surface area, increase pressure of gases, increase temperature.
45
What does the half-life of a 1st order process depend on?
It is constant regardless of the initial concentration.
46
What does a larger activation energy indicate about a reaction's speed?
The slower the reaction.
47
What is the equilibrium constant expression for a reaction?
Keq = [products]x/[reactants]y.
48
What does a large Keq value indicate?
There are more products at equilibrium.
49
What is Le Chatelier's Principle?
If Q > Keq, the reaction shifts to the left towards the reactants.
50
What is the pH range for acids and bases?
Acids are less than 7; bases are greater than 7.
51
What do strong acids do?
They donate [H+].
52
What is the relationship between acid strength and its conjugate base?
The stronger the acid, the weaker its conjugate base.
53
What does a larger Ka value imply?
A stronger acid.
54
What happens to % ionization of a weak acid as the acid concentration decreases?
It increases.
55
What characterizes salts containing conjugate bases of weak acids?
They are slightly basic.
56
What is the formula for calculating pH?
pH = −log [H+].
57
What does the shortcut [H+] = Square Root of MaKa apply to?
It applies if 'x' is small compared to Ma.