thermal Flashcards

(29 cards)

1
Q

define internal energy

A

the sum of randomly distributed potential and kinetic energies of the particles in a body

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2
Q

how does the internal energy of the system increase

A

-heat energy is transferred
-work is done on the system

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3
Q

equation of first law of thermodynamics

A

Q=change in U+W
U=internal energy
W=work done by the system
Q=heat added

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4
Q

define specific heat capacity

A

the amount of energy required to increase the temperature of 1 kg of the substance by 1C without changing its state

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5
Q

define specific latent heat of fusion/vaporisation

A

energy required to change the state of 1 kg of the substance from _ to _ without changing its temperature

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6
Q

how to calculate delta theta

A

final temperature - initial temperature

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7
Q

what cancels out in the continuous flow calorimeter calculation

A

heat loss, as in this experiment delta theta is set to be constant so heat loss is also constant

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8
Q

explain why an electric motor become warm when it is used

A

-work is done by the magnetic field
-electrons collides and gives up some of their energy in the wire

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9
Q

describe the energy transfer in the electric motor

A

-electrical energy converted to kinetic energy and heat energy in the motor,
-heat energy transferred to the surrounding from the motor

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10
Q

what is absolute zero temperature

A

0K,=-273C

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11
Q

what is Boyle’s law

A

p1V1=p2V2, constant temperature

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12
Q

what is Pressure’s law

A

p1/T1=p2/T2

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13
Q

what is Charles’s law

A

V1/T1=V2/T2

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14
Q

the steeper the gradient in volume against temperature graph means that

A

the lower the pressure

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15
Q

the further the curve away from the origin in pressure against volume graph

A

the higher the temperature

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16
Q

difference between n and N

A

n=moles , N=number of molecules, N=Avogadro*n

17
Q

equation for work done

A

W=p*change in V

18
Q

define Avogadro’s constant

A

the number of molecules in one mole of a substance/ the number of atoms in 12g of carbon-12

19
Q

For ideal gas, all molecules of a gas are identical so they have the same

A

mass and change in momentum on average

20
Q

describe the motion of ideal gas

A

molecules move in random motion

21
Q

How do ideal gas collide

A

elastic collision, KE is conserved

22
Q

How does it mean when ideal gas said to be following the newton’s 1st law

A

the molecules move in straight

23
Q

assumption on the volume for ideal gas

A

the volume of molecules is negligible compared to the volume of the gas

24
Q

large amount of molecules for ideal gas so

A

constant force on the wall

25
what can we say about the attraction between molecules in ideal gas
no attraction so potential energy is zero
26
assumption on time for ideal gas
the duration of collisions is negligible compared to the time between each collisions
27
how to derive pV=1/3Nm(c rms)^2
-change in momentum for each molecules -one round trip in t time -times them to get the total change in momentum of one molecule -divide the total N by 3 as molecules move in random motion -time it by the total change in momentum -find F , F=mv/t -find p, substitute in V
28
equation for total kinetic energy of molecule in ideal gas
KE=3/2nRT
29
methodology for answering KE model explanation
-effects on collisions per second/mean KE due to___ - effects on change in momentum and rate of change in momentum -force is proportional to pressure