thermo dynamics Flashcards
thermodynamics
study of heat changes that take place during a chemical reaction
heat of reaction
the heat change that occurs during the course of a chemical reaction when the reaction occurs completely according to the balanced equation
bond energy
average energy required to break one mole of a particular covalent bond and to separate the neutral atoms completely from each other
exothermic
reactants greater than products so extra energy left in system so this is released as heat hence delta h is minus
endothermic
products higher that reactants so not enough energy in system hence heat is absorbed from surrounding so delta h is positive
heat of combustion
the heat change that occurs when 1 mole of a substance in completely burned in excess oxygen
simple calorimeter
a vessel of negligible heat capacity which acts as an insulator and prevents a heat exchange between the system and the surroundings
kilogram calorific value
heat energy produced when 1 kg of fuel is completely burned in excess oxygen
heat of neutralisation
the heat change that occurs when 1 mol of h+ ions of an acid reacts with 1 mole of oh- ions from a base