Thermodynamics Flashcards

(58 cards)

1
Q

The co-efficient B in the volume, thermal expansion formula is what?

A

3a

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2
Q

Zeroth Law

A

if Ta=Tb and Tb=Tc then Ta=Tc and they are all in thermal equilibrium

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3
Q

Ideal Gas Law

A

particles don’t interact

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4
Q

Ideal Gas

A

low density
pressure is less than 1 atm
temp is not near boiling point

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5
Q

Avogadro’s Law

A

volume of gas at same T and P has same N of particles no matter type of gas

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6
Q

relation to PVT for 1 gas and 2 gas

A

P1V1/T1=P2V2/T2

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7
Q

Kinetic Theory of Gases

A

all particles always in motion

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8
Q

Kinetic Theory of Gases applied to the 5 following ideal gas assumptions

A

particles :
don’t rotate or vibrate
don’t interact
elastic collisions for short t with wall
free to move in any direction
identical particles and large amount

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9
Q

How to find the vrms?

A

square all the velocities, take the average of that, take square root of that

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10
Q

Mean free path

A

mean length of straight part of molecules path

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11
Q

Mean Free Time

A

average time between collision

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12
Q

Diffusion

A

mix of particles

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13
Q

Can ideal gases change phases? Why?

A

No because they don’t exert forces on one another

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14
Q

Solid to vapor

A

Sublimation

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15
Q

Liquid to Gas

A

Evaporating

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16
Q

Gas to liquid

A

Liquification

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17
Q

for a phase change if gas temperature is greater/lower than critical tempt gas cannot go to a liquid

A

greater

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18
Q

on a muggy day there is what

A

increase water vapor

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19
Q

relative humidity formula

A

Pwater/Psup x100%

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20
Q

1st law of thermodynamics key 1 pt

A

work up-work down= w out

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21
Q

2nd law of thermodynamics relates to

A

entropy never decreases, change in entropy always greater than/equal to 0

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22
Q

entropy is the

A

disorderness

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23
Q

cold air cannot flow from cold to hot unless

A

work is done

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24
Q

no perfect ___ exists

A

100% efficient engine

25
2nd law of thermodynamics also talks about the fact an engine can never exceed the
carnot engine
26
3rd law of thermodynamics says there cannot be
a perfect engine
27
equipartition of energy degrees of freedom what 4 types
translational Ke rotational Ke vibrational Ke vibrational Pe
28
all active degrees of freedom have
equal energy
29
energy of a degree of freedom formula
1/2kBT
30
f of a monotomic and diatomic
3, 5
31
Cv of a monotomic and diatomic
3k/2, 5k/2
32
Cp of a monotomic and diatomic
5k/2, 7k/2
33
y of a monotomic and diatomic
1.67, 1.4
34
Number of degrees freedom at low temp, room temp, high temp
1,5,7
35
why are there only 5 degrees of freedom at room temp?
quantum effects preventing vibrational modes being active at these temps
36
specific heat unit and what it is?
c, amount of heat required to raise 1kg by 1K
37
molar specific heat unit and what it is?
C, amount of heat required to raise 1 mole by 1K
38
is there a subscript on molar-specific heat for liquids or solids?
no only v and p for gases
39
R=?
Cp-Cv
40
latent heat
amount of E required for a phase change
41
what does it mean if Q is negative?
heat going from system to environment
42
during a phase change 3 pts
T is constant E internal changes amount of Q=Q transferred to/from each kg of material
43
Q=...
mc change in temp
44
adiabatic
Q=0
45
adiabatic compression
temp increases
46
isothermal ___ so
change temp=0, tf=ti so change eth=0
47
isochronic ___ so
change in volume=0,wtot=0
48
isochronic on a PV diagram is
|
49
isobaric
change in pressure=0
50
isobaric on a PV diagram is
_
51
conduction is molecules...
vibrating due to collisions
52
the insulator has high or low k
low
53
the conductor has high or low k
high
54
convection is
heat transported through the motion of fluids
55
heat engine e formula
Weng/Qh=(Qh-Qc)/Qh=1-(Qh/Qc)
56
e carnot=
1-Tc/Th or Th-Tc/Th x100%
57
refrigerator k
Qc/W= Qc/Qh-Qc
58
heat pump k
Qh/W= Qh/Qh-Qc