thermodynamics Flashcards

(35 cards)

1
Q

calorimetry

A

the measurement of heat changes

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2
Q

chemical energy

A

energy stored within the structural units of chemical substances

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3
Q

closed system

A

a system that enables exchange of energy (usually in the form of heat) but not mass with its surroundings

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4
Q

endothermic process

A

processes that absorb heat from the surroundings

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5
Q

energy

A

the capacity to do work or to produce change

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6
Q

enthalpy

A

a thermodynamic quantity used to describe heat changes taking place at a constant pressure

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7
Q

enthalpy of reaction

A

the difference between the enthalpies of the products and the enthalpies of the reactants

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8
Q

enthalpy of solution

A

the heat generated or absorbed when a certain amount of solute dissolved in a certain amount of solvent

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9
Q

exothermic process

A

processes that give off heat to the surroundings

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10
Q

first law of thermodynamics

A

energy can be converted from one form to another, but can not be created or destroyed

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11
Q

heat

A

transfer of energy between two bodies that are at different temperatures

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12
Q

heat capacity

A

the amount of heat required to raise the temperature of a given quantity of a substance by one degree celsius

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13
Q

heat of diluation

A

the heat change associated with the dilution process

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14
Q

heat of hydration

A

the change associated with the hydration process

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15
Q

heat of solution

A

the heat generated or absorbed when a certain amount of solute is dissolved in a certain amount of solvent

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16
Q

hess’s law

A

when reatants are converted to products the change in enthalpy is the same, whether the reaction takes places in one step or in series of steps

17
Q

isolated system

A

a system that does not allow the transfer of energy of either mass or energy to or from its surroundings

18
Q

lattice energy

A

the energy required to completely separate one mole of a solid ionic compound into gaseous ions

19
Q

law of conservation of energy

A

the total quantity of energy in the universe is constant

20
Q

open system

A

a system that can exchange mass and energy (usually in the form of heat) to its surroundings

21
Q

potential energy

A

energy available by virtue of an objects position

22
Q

radiant energy

A

energy transmitted in the form of waves

23
Q

specific heat

A

the amount of heat energy required to raise the temperature of one gram of a substance by one degree celsius

24
Q

standard of enthalpy of formation

A

the heat change that results when one mole of a compound is formed from its elements in their standard states

25
standard of enthalpy of reaction
the entropy change when the reactions is carreid out under standard state conditions
26
standards of state
the condition of 1 atm of pressure
27
state function
a property that is determined by the state of the system
28
state of a system
the values of all pertinent macroscopic variables of a system (pressure, temp, volume composition)
29
surroundings
the rest of the universe outisde a system
30
system
any specific part of the system that is of interest to us
31
thermal energy
energy associated with the random motion of atoms and molecules
32
thermochemical equation
an equation that shows both the mass and the enthalpy relations
33
thermochemistry
the study of heat changes in chemical reactions
34
thermodynamics
the scientfic study of the interconversion of heat and other forms of energy
35
work
directed energy change resulting from a process