thin layer chromatography Flashcards

(12 cards)

1
Q
A
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2
Q

what is visualisation of TLC

A

where somethin needs to be done to temporarily see the comounds

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3
Q

uses of TLC

A

to assess reaction progress to determine if reactants have been consumed to form a new product

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4
Q

what is a co spot

A

where reactant and product are spotted on top of each other

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5
Q

what is the retention factor

A

how chemists report the result of TLC plate , as R value, where the Rf = distance travelled by the compound/distance travelled by the solvent

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6
Q

what does an Rf value of 0.55 mean

A

the spot moved 55% as far as the solvent front

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7
Q

what is the order of elution on silica TLC plates

A

less polar is higher, more polar is lower

silica attracts polar compounds

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8
Q

describe betweeb benzyl alcohol, benzaldehyde and ethylbenzene which will elute from TLC plate the quickest

A

benzyl alcohol = most polar - retained the most

benzaldehyde = moderately polar so can be carried further by the mobile phase

ethylbenzene = least polar - travels with mobile phase

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9
Q

what are the functional groups polarity

A

increasing n polarity

alkanes
alkenes
aromatic hydrocarbons
ethers, halocarbons
aldehydes, ketones, esters
amines
alcohols
carboxylic acids

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10
Q

is amide or amine more polar

A

amide is more polar, bc it can hydrogen bond and accept hydrogen bonds on oxyden and nitrogen

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11
Q

structure of amide group?

A

has a carbonyl group bonded to nitrogen atom

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12
Q
A
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