TOPIC 13- ELECTROCHEMISTRY Flashcards

(27 cards)

1
Q

is the study of the relationships between electricity
and chemical reactions
. It includes the study of both spontaneous and
nonspontaneous
processes.

A

Electrochemistry

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2
Q

is the loss of electrons. (oxidation number increases)

A

Oxidation

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3
Q

is the gain of electrons. (oxidation number decreases)

A

Reduction

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4
Q

The oxidizing agent is __________, and the reducing agent is _________.

A

reduced, oxidized

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5
Q

its purpose is to keep track of what loses electrons and what gains them

A

Oxidation Numbers

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6
Q

increase in oxidation numbers means

A

oxidized

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7
Q

decrease in oxidation numbers means

A

reduced

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8
Q

What are the electrochemical cells?

A
  1. Voltaic Cell
  2. Electrolytic Cell
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9
Q

Energy is released from a
spontaneous redox reaction and Work is done by the system on the load.

A

voltaic cell

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10
Q

Energy is absorbed from a
nonspontaneous redox reaction and work is done on the system by the load.

A

Electrolytic Cell

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11
Q

In a _________, the mass of the anode decreases over time as it turns
into ions, while the mass of the cathode increases.

A

voltaic cell

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12
Q

In voltaic cell, the electrical flow is always

A

from the anode to the cathode

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13
Q

In Electrolytic Cell, the electrical flow is

A

from the cathode to the anode

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14
Q

have values corresponding to reduction half-reactions with all solutes at 1 M and all gases at 1 atm.

A

Standard reaction potentials 𝐸𝑐𝑒𝑙𝑙

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15
Q

The more positive the value of the standard reduction potential, the greater the tendency for β€”β€”β€” under standard conditions.

A

reduction

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16
Q

have the most positive reduction potentials.

A

strongest oxidizers

17
Q

have the most negative reduction potentials.

A

strongest reducers

18
Q

The cell potentials of β€”β€”- are higher than those of the cathodes.

19
Q

The cell potential in a voltaic cell is

A

always positive

20
Q

The increase and decrease of concentration is _____________ to cell
potential

A

directly proportional

21
Q

When the concentration of reactants is increased, both the electron driving
force and cell potential __________.

(products are favored, shifts right)

22
Q

When the concentration of the products is increased, both the electron
driving force and cell potential —–.

(reactants are favored, shifts left)

23
Q

Both compartments of ___________
have the same components but at different
concentrations.

A

concentration cells

24
Q

is the only factor
that produces a cell potential.

A

Difference in concentration

25
The electrons flow in the direction that tends to
equalize the concentration
26
Oxidation occurs on the
dilute solution
27
gives the relationship between the cell potential and the concentrations of the cell components.
nernst equation