topic 2 recap Q. structure and bonding Flashcards

1
Q

What is a covalent bond?

A

a shared pair of electrons

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2
Q

which type of atoms form covalent bonds?

A

non-metals

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3
Q

why do simple covalent substances not conduct electricity?

A

do not have delocalised electrons.

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4
Q

describe the structure and bonding of small molecules

A

small molecules with strong covalent bonds between the atoms and weak intermolecular forces between molecules

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5
Q

what is an ion?

A

an atom that has lost or gained electrons

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6
Q

what charges do ions from group 1 and 2 form?

A

+1
+2

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7
Q

why do small molecules have low melting points?

A

only a small amount of energy is needed to break the weak intermolecular forces

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8
Q

what charges do ions from group 6 and 7 form?

A

2-
1-

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9
Q

name the force that holds oppositely charged ions together?

A

electrostatic forces of attraction

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10
Q

which kinds of elements form ionic bonds?

A

metals and non-metals

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11
Q

describe the structure of a giant ionic lattice?

A

alternating positive and negative ions, held together by the electrostatic force of attraction

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12
Q

why do ionic substances have high melting points?

A

the electrostatic force is strong and needs alot of energy to break

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13
Q

why dont ionic substances conduct electricity when solid?

A

ions are in a fixed position so cannot move, and there are no delocalised electrons

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14
Q

when can ionic substances conduct electricity?

A

when melted or dissolved

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15
Q

why do ionic substances conduct electricity when molten or dissolved?

A

ions are free to move and carry charges

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16
Q

describe the structure of a pure metal?

A

strong electrostatic forces of attraction between metal ions and delocalised electrons

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17
Q

describe the bonding of a pure metal

A

layers of positive metal ions surrounded by delocalised electrons

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18
Q

what are the four properties of pure metals?

A

malleable
high melting/boiling point
good conductors of electricity
good conductors of thermal energy

19
Q

explain why alloys are harder then pure metals

A

different sized atoms disturb the layers which prevents them from sliding over each other

20
Q

explain why pure metals are malleable

A

layers can slide

21
Q

explain why metals have high melting and boiling points

A

electrostatic forces of attraction between positive metal ions and delocalised electrons is strong

22
Q

why are metals good conductors of electricity?

A

delocalised electrons are free to move and carry charge

23
Q

why are metals good conductors of thermal energy?

A

delocalised electrons are free to move and transfer thermal energy

24
Q

what is an alloy?

A

a mixture of a metal with another element

25
describe the structure and bonding of a giant covalent substances
billions of atoms bonded together by strong covalent bonds
26
describe the structure and bonding of polymers
many identical molecules joined together by strong covalent bonds in a long chain, with weak intermolecular forces between the chains
27
why do giant covalent substances have high melting points
it takes alot of energy to break the strong covalnt bonds
28
explain why graphite is soft
layers are not bonded so they can slide over each other
29
why do large molecules have higher melting and boiling points than small molecules?
the intermolecular forces are stronger
29
why do most covalent substances not conduct electricity?
they do not have delocalised electrons or ions
30
describe the structure and bonding in graphite?
each carbon atom is bonded to 3 others in a hexagonal ring arranged in layers. each atom delocalises one electron and the forces between layers are weak
31
why can graphite conduct electricity
1 delocalised electron per carbon
32
what is graphene
one layer of graphite
33
give two properties of graphene
strong conducts electricity
34
what is fullerene?
hollow cage of carbon atoms arranged in a sphere or tube
35
what is a nanotube?
hollow cylinder of carbon atoms
36
how big are nanoparticles?
1-100 nm
37
give two properties of nanotubes
high tensile strength conduct electricity
38
how are nanomaterials different from bulk materials?
nanomaterials have a higher surface area-to-volume ratio
39
what is the relationship between side length and surface area-to-volume ratio?
as the side length decreases by a factor of 10 the surface area-to-volume increases by a factor of 10
40
what are nanoparticles use for?
healthcare electronics cosmetics catalysts
41
how big are fine particles?
100-2500 nm
42
give 3 uses of fullerenes
lubricants drug delivery electronics
43
how big are course particles?
2.5 x 10-6 to 1 x 10-5