Topic 3 Flashcards

Evaluating Properties (49 cards)

1
Q

Substance that has a fixed chemical
composition throughout

A

Pure Substance

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2
Q

A mixture of various chemical
elements or compounds also
qualifies as a pure substance as long
as the mixture is

A

Homogeneous

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3
Q

Does not have to be of a single
chemical element or compound.

A

Pure Substance

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4
Q

Major Components in Dry Air

A

Nitrogen - 78.08%
Oxygen - 20.95
Argon - 0.93%
Other - 4%

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5
Q

Minor Components in Dry Air (Other 4%)

A

Carbon Dioxide - 0.033%
Neon - 0.0018%
Helium - 0.0005%
Methane - 0.0002%
Krypton - 0.0001%
Hydrogen - 0.00005%
Xenon - 0.000009%

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6
Q

any mixture that is uniform in
composition throughout.

A

Homogeneous mixture (solutions)

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7
Q

3 principal phases

A

Solid, Liquid, Gas

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8
Q

quantity of matter that is
homogeneous throughout in both
chemical composition and physical
structure

A

Phase

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9
Q

strong intermolecular bond

A

Solid

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10
Q

intermediate intermolecular bonds

A

Liquid

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11
Q

weak intermolecular bond

A

Gas

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12
Q

the temperature and pressure above which there is no distinction between the liquid and vapor phases.

A

Critical Point

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13
Q

the temperature and pressure at which all three
phases can exist in equilibrium.

A

Triple Point

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14
Q

change of phase from solid to vapor.

A

Sublimation

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15
Q

change of phase from liquid to vapor.

A

Vaporization

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16
Q

change of phase from vapor to liquid.

A

Condensation

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17
Q

change of phase from solid to liquid.

A

Fusion or Melting

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18
Q

a point on a phase diagram at which both the liquid and gas phases of a substance have the same density, and are therefore indistinguishable.

A

Critical Point

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19
Q

condition in which a mixture of vapor
and liquid can exist together at a given
temperature and pressure.

A

Saturation

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20
Q

the pressure at which the liquid and
vapor phases are in equilibrium at a
given temperature

A

Saturation pressure

21
Q

Saturation

A

 For a pure substance there is a
definite relationship between
saturation pressure and saturation
temperature.

 The higher the pressure, the higher
the saturation temperature

22
Q

If a substance exists as a liquid at the
saturation temperature and pressure

A

Saturated Liquid

23
Q

If the temperature of the liquid is
lower than the saturation temperature
for the existing pressure

A

sub cooled liquid or compressed liquid.

24
Q

If a substance exists entirely as
vapor at saturation temperature

A

Saturated Vapor

25
When the vapor is at a temperature greater than the saturation temperature
Superheated vapor
26
Pressure and temperature of superheated vapor
- are independent properties, - temperature may increase while the pressure remains constant
27
amount of energy absorbed or released during a phase-change process.
Latent Heat
28
Latent heat of fusion
- amount of energy absorbed during melting. - equivalent to the amount of energy released during freezing.
29
Latent heat of vaporization
- amount of energy absorbed during vaporization - equivalent to the energy released during condensation.
30
Latent Heat
At 1 atm pressure latent heat of fusion of water 333.7 kJ/kg latent heat of vaporization 2256.5 kJ/kg.
31
ratio of the mass of the vapor to the total mass of both vapor and liquid.
Quality
32
Quality
When a substance exists as part liquid and part vapor at saturation conditions
33
Moisture Content
The moisture content of a substance is the opposite of its quality.
34
defined as the ratio of the mass of the liquid to the total mass of both liquid and vapor
Moisture content
35
any extensive property
Y
36
corresponding intensive property
y
37
v < vf
Compressed Liquid
38
vf < v < vg
Saturated Liquid
39
v > vg
superheated
40
x = 0.0
Saturated Liquid
41
states the pressure of a gas expanding at constant temperature varies inversely to the volume,
Ideal Gas Law
42
Robert Boyle
Ideal Gas Law P1V1 = P2V2 = constant
43
Jacques Charles
concluded that the pressure of a gas varies directly with temperature when the volume is held constant, and the volume varies directly with temperature when the pressure is held constant
44
Jacques Charles
V1 / V2 = T1 / T2 or P1 / P2 = T1 / T2
45
universal gas constant
Ru R = Ru / M
46
Specific heat at constant volume
Cv (for a constant-volume process)
47
Specific heat at constant pressure
Cp (for a constant - pressure process)
48
specific heat ratio
k k = Cp / Cv
49
functions of temperature alone
u, h, Cv, and Cp