Topic 4 - Extracting metals and Equilibria Flashcards
(51 cards)
What is really mesured in the reactivity series?
How easily the metals form positive ions -> how easily they react
Displacement reactions
When more reactive metals replace less reactive metals.
How do you extract metal ores that are less reactive than carbon?
Reduction with carbon
1.
How do you extract metal ores that are more reactive than carbon?
electrolysis
What happens in reduction with carbon?
It switches with the metal oxide to form carbon dioxide, leaving the metal by itself, rreduced.
Bio-leaching
Uses bacteria to seperate metals from their ores, e.g. copper can be seperated from copper sulfate this way. The bacteria get energy from the bonds between atoms in the ore, seperating out the metal from the ore in the process. The leachate produced contains metal ions that can be extracted (e.g. electrolysis or displacement)
a Bacterial method of extracting metals
Phyto-mining
Involves growing plants in soil that contains metal compounds. The plants can’t use or get rid of metals so they gradually build up in leaves. The plants can be harvested, dried and burned in a furnace. The ash contains metal compounds from which the metal can be extracted (by electrolysis or displacement reactions)
What is a reversible reaction?
where the products can react with eachother to create the original reactants ( it goes both ways)
What is an example of an industrial reversible reaction?
The Haber process:
N2+3H2 ⇌ 2NH3 ( + Heat )
Where are the reactants come from in the Haber process?
Nitrogen - easily from air, about 78% N
Hydrogen - From Hydrocarbons e.g. natural gas and crude oil
What are the conditions for the Haber process?
450”C
Pressure - 200 atm
Iron Catalyst
Why is equilibruim reached in Reversible reactions?
As (reactants or Products) React, their concentration will fall, the other products concentration will rise, leading to their rate of reaction to increase.
What is Dynamic equilibrium?
The forward and backward reactions are both happening at the same time and at the same rate, and the concentration of both have reached a balance and wont change
in what conditions can equilibrium be reached?
In a closed system
What 3 things can change position of equilibrium?
Temperature
Pressure (For GASES)
Concentration
Ho
How does temperature affect Equilibruim
Higher temperature favours the Endothermic side
to absorb more heat
How does Pressure affect equilibrium?
( IN GASES ONLY) Raising pressure favour side of least moles to lower pressure
How does concentration affect equilibrium?
If you increase the conc of reactants the equilibrium will shift tothe right to use up the reactants
What is oxidation?
The reaction with, or addition with oxygen
What is reduction?
can be the removal of oxygen
What do combustion reactions involve?
Oxidation + reduction of oxygen
Exothermic
What is the reactivity series ?
a table that lists metals in order of their reactivity
Why is Carbon often included in the reactivity series?
Because a metals position in the reactivity series compared to carbon dictates how its extracted from ore
Hydrogen may also be included
What is the reactivity series ( with dilute acids)?
The Reactivity Series
Potassium. - K
Sodium. - Na
Calcium. - Ca
Magnesium. - Mg
Aluminium. - Al
Carbon. - C
Zinc. - Zn
Iron - Fe
Hydrogen - H
Copper - Cu
Silver - Ag
Gold. - Au
Top : Least resistant to oxidation / Most reactive