Topic 8 Flashcards

1
Q

what is meant by enthalpy

A

The total chemical energy inside a substance

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2
Q

For an Exothermic reaction what is the enthalpy change

A

negative

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3
Q

For an endothermic reaction what is the enthalpy change

A

Posistive

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4
Q

what is standard enthalpy change of reaction

A

Chnage which occurs when equation quantites of material react under standard conditions & with everything in it’s standard state

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5
Q

what is standard enthalpy change of formation

A

Enthalpy change when one mole of a compound is formed from its elements under standard conditions.

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6
Q

what is standard enthalphy change of combustion

A

Enthalpy change when one mole of a compound burns completely in oxygen under standard conditions.

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7
Q

what is standard enthalpy change of neutralisation

A

Enthalpy change when the acid and alkali in the reaction neutralise each other in standardised conditions to form 1 mole of water.

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8
Q

what is bond dissassociation enthalpy

A

Enthalpy change when a covalent bond is broken with all species being in gaseous state

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9
Q

what is mean bond enthalpy

A

Enthalpy change when 1 mole of a covalent bond is broken & averaged over range of molecules

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10
Q

what is Hess’s Law

A

Enthalpy change of a chemical reaction at constant pressure is dependant of the route taken & depends on the initial & final states

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11
Q

what can we do to test if the cycles are correct

A
  • Start anywhere on the cycle & add any number until you reach where you were
  • If you go against the arrow switch the sign
  • If correct it should be equal to zero
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