Total Resins Flashcards
(35 cards)
What are the two main subdivisions of total resins?
Soft resins and hard resins
In which solvent are soft resins soluble?
Hexane
In which solvent are hard resins soluble?
Methanol
What components are soft resins split into?
α-acids, β-acids and uncharacterised components
What is the test used to quantify the amount of each component in hops?
Lead conductance value of hops
What do α-acids form when mixed with lead acetate?
A yellow precipitate
What are the α-acids called?
Humulones
What are the homologs of humulones?
- Humulone
- Cohumulone
- Adhumulone
What are the β-acids called?
Lupulones
What are the homologs of lupulones?
- Lupulone
- Colupulone
- Adlupulone
Why are α-acids considered the most important constituents of hop resins?
They become isomerised into more soluble and bitter iso-α-acids during wort boiling
What is isomerisation?
One molecule is transformed into another molecule containing exactly the same atoms, but with a different arrangement
What are the two ways isomerisation of hops occurs?
- During wort boiling
- Heating α-acids with a magnesium or potassium salt in an alkaline solution
What is the ratio of cis to trans isomers in isomerised hops?
Roughly 70:30
What are diastereomers?
Cis and trans isomers that are not mirror images of each other
What is the isomerised form of humulone?
Isohumulone
What is the solubility characteristic of Cohumulone?
It has the highest solubility and utilisation due to its more polar character
True or False: Cis-isomers are less stable than trans-isomers.
False
Which iso-α-acid is more bitter: isohumulone or isocohumulone?
Isohumulone
What is the typical hop utilisation percentage in beer produced using a standard brewing process?
Around 30-35%
How is hop utilisation calculated?
% Hop Utilisation = (Mass of iso-α-acids in wort or beer / Mass of α-acids added to wort) x 100
What pH level can provide up to 90% hop utilisation?
A pH of 8-10
What effect does boil time have on hop utilisation?
Longer boil time increases utilisation, up to a maximum of around 4 hours
How does wort gravity affect hop utilisation?
Hop utilisation is greater in lower gravity worts