transition metal ions Flashcards

(29 cards)

1
Q

Ti3+

A

purple

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2
Q

V2+

A

purple

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3
Q

V3+

A

green

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4
Q

V4+

A

blue

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5
Q

V5+

A

yellow

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6
Q

Cr2+

A

blue

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7
Q

Cr3+

A

green

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8
Q

Cr6+

A

orange

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9
Q

Mn2+

A

pale pink

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10
Q

Mn6+

A

green

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11
Q

Mn7+

A

violet

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12
Q

Mn4+

A

brown

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13
Q

Fe2+

A

pale green

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14
Q

Fe3+

A

yelloq

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15
Q

Co2+

A

pink-purple

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16
Q

Co3+

17
Q

Ni2+

18
Q

Cu2+

19
Q

how do you write a Kp expression?

A

H2 + I2 –> –< 2HI
Kp = p(HI)2
————-
p(H2) p(I2)

20
Q

what happens to the value of the rate constant k when temperature increases?

A

it increases. for many reactions increasing the temperature by 10C doubles the rate constant

21
Q

what happens to K if the temperature increases when the forward reaction is exothermic?

A

K will decrease, the equilibrium yeild of products will decrease.

22
Q

what happens to K if the temperature increases when the forward reaction is endothermic?

A

the equilibrium constant increases, the equilibrium yeild of products increases.

23
Q

what is the effect on K of increasing the pressure/concentration in a system?

A

K will not change. when the concentration increases the system is no longer in equilibrium. the concentrations change to return the ratio back to the K value. this means the position of equilibrium will change but not the value of Kc or Kp.

24
Q

define the term standard enthalpy change of formation

A

the enthalpy change that takes place when one mole of a compound is formed from its elements under standard conditions, with all reactants and products in their standard states.

25
define the term standard enthalpy change of atomisation
the enthalpy change that takes place when one mole of gaseous atoms are formed from the element in its standard state under standard conditions
26
define the term first ionisation energy
the enthalpy change required to remove one electron from each atom in a mole of gaseous atoms to form a mole of gaseous +1 ions
27
define the term first electron affinity
the enthalpy change that takes place when one electron is added to each atom in a mole of gaseous atoms to form gaseous 1- ions
28
define the term enthalpy change of solution
the enthalpy change that takes place when one mole of a solute dissolves in a solvent, forming aqueous ions
29
what is the entalpy change of hydration?
the enthalpy change that accompanies the dissolving of gaseous ions to form one mole of aqueous ions