Transition metals colours Flashcards

(33 cards)

1
Q

Cu2+ in aqueous solution

A

light blue sol

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2
Q

Co2+ in aqueous solution

A

pale pink sol

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3
Q

Fe2+ in aqueous solution

A

pale green sol

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4
Q

Fe3+ in aqueous solution

A

yellow sol

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5
Q

Cr3+ in aqueous solution

A

dark green sol

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6
Q

formation of 2+ ions in aqueous solution

A

[M(H2O)6] 2+

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7
Q

formation of 3+ ions in aqueous solution

A

[M(H2O)6] 3+

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8
Q

Cu2+ in limited OH

A

blue ppt

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9
Q

Co2+ in limited OH

A

blue ppt

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10
Q

Fe2+ in limited OH

A

green ppt

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11
Q

Fe3+ in limited OH

A

brown ppt

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12
Q

Cr3+ in limited OH

A

green ppt

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13
Q

formation of 2+ ions in limited OH

A

[M(OH)2(H2O)4]2+

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14
Q

formation of 3+ ions in limited OH

A

[M(OH)3(H2O)3]

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15
Q

Cu2+ in excess NH3

A

royal/dark blue sol

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16
Q

Co2+ in excess NH3

A

red/brown sol

17
Q

Fe2+ and Fe3+ in excess NH3

18
Q

Cr3+ in excess NH3

19
Q

Cu2+ in excess NH3 displayed incomplete ligand substitution.

what is the formation of this complex ion

A

[Cu(Nh3)4(H2O)2]2+

20
Q

Co2+ in excess NH3
what is the formation of the complex ion

21
Q

Cr3+ in excess NH3
what is the formation of the complex ion

22
Q

Cu2+, Co2+, Fe2+, Fe3+ all in excess OH (acid-base)

23
Q

Cr3+ in excess OH (acid-base) colour

24
Q

Cr3+ in excess OH (acid-base) colour

ALKALI (OH-) equation

A

Cr(H2O)3(OH)3 (s) + 3OH- (aq) —> [Cr(OH)6]3- (aq) + 3H2O (l)

25
Cr3+ in excess OH (acid-base) colour ACID (H+) equation
Cr(H2O)3(OH)3 (s) + 3H+ (aq) ---> [Cr(H2O)6]3+ (aq)
26
Cu2+ and Fe3+ redox
X
27
Co2+ redox colour
D. brown sol
28
Fe2+ redox colour
orange ppt
29
Cr3+ redox colour
yellow sol (wH2O2) CrO42-
30
Co2+ and Fe2+ redox complex ion formula
M(OH)3(H2O)3
31
Cu2+ in Cl- ions colour
green sol
32
Co2+ in Cl- ions colour
blue sol
33
Cu2+ and Co2+ in Cl- ion formation and shape
[MCl4]2- tetrahedral