Transition metals colours Flashcards
(33 cards)
Cu2+ in aqueous solution
light blue sol
Co2+ in aqueous solution
pale pink sol
Fe2+ in aqueous solution
pale green sol
Fe3+ in aqueous solution
yellow sol
Cr3+ in aqueous solution
dark green sol
formation of 2+ ions in aqueous solution
[M(H2O)6] 2+
formation of 3+ ions in aqueous solution
[M(H2O)6] 3+
Cu2+ in limited OH
blue ppt
Co2+ in limited OH
blue ppt
Fe2+ in limited OH
green ppt
Fe3+ in limited OH
brown ppt
Cr3+ in limited OH
green ppt
formation of 2+ ions in limited OH
[M(OH)2(H2O)4]2+
formation of 3+ ions in limited OH
[M(OH)3(H2O)3]
Cu2+ in excess NH3
royal/dark blue sol
Co2+ in excess NH3
red/brown sol
Fe2+ and Fe3+ in excess NH3
X
Cr3+ in excess NH3
purple sol
Cu2+ in excess NH3 displayed incomplete ligand substitution.
what is the formation of this complex ion
[Cu(Nh3)4(H2O)2]2+
Co2+ in excess NH3
what is the formation of the complex ion
[Co(NH3)6]2+
Cr3+ in excess NH3
what is the formation of the complex ion
[Cr(NH3)6]3+
Cu2+, Co2+, Fe2+, Fe3+ all in excess OH (acid-base)
X
Cr3+ in excess OH (acid-base) colour
green sol
Cr3+ in excess OH (acid-base) colour
ALKALI (OH-) equation
Cr(H2O)3(OH)3 (s) + 3OH- (aq) —> [Cr(OH)6]3- (aq) + 3H2O (l)