True or False Exam 3 Flashcards

(48 cards)

1
Q

A higher concentration of buffer components gives a better buffer capacity.

A

true

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2
Q

the H2PO4-/HPO4-2 bufer si common ni living systems.

A

true

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3
Q

for a buffer solution, when the conjugate ratio is one, then pH = pKa.

A

true

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4
Q

increasing the ratio of the conjugate pair (base/acid) wil decrease the pH of a buffer solution.

A

false

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5
Q

The addition of strong acid to a buffer solution increases the pH of the solution.

A

false

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6
Q

Dilution favors that side of an equation which has more gas or solute particles.

A

True

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7
Q

For every equilibrium system, decreasing the volume wil shift the equilibrium position to the right.

A

false

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8
Q

For an exothermic process, the equilibrium constant will increase at higher temperatures.

A

false

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9
Q

Adding more solid reactant to a system increases Q.

A

false

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10
Q

consider the following system at equilibrium.
BaSO,(5) + H(aq) = Ba?(aq) + HSO4(aq) ДН° = 48.2 kJ
Wil the following actions favor a shift to the right side, to the left side, or have no such effect? DECREASE TEMPERATURE

A

left

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11
Q

Consider the following system at equilibrium.
BaSO,(5) + H(aq) = Ba?(aq) + HSO4(aq) ДН° = 48.2 kJ
Wil the following actions favor a shift to the right side, to the left side, or have no such effect? ADD A SOULUBLE BARIUM SALT

A

left

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12
Q

Consider the following system at equilibrium.
BaSO,(5) + H(aq) = Ba?(aq) + HSO4(aq) ДН° = 48.2 kJ
Wil the following actions favor a shift to the right side, to the left side, or have no such effect? INCREASE THE AMOUNT OF WATER SOLVENT

A

right

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13
Q

Consider the following system at equilibrium.
BaSO,(s) + H(aq) = Ba?(aq) + HSO4(aq) ДН° = 48.2 kJ
Wil the following actions favor a shift to the right side, to the left side, or have no such effect? ADD MORE BaSO4(s)

A

no effect

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14
Q

Consider the following system at equilibrium.
PA(s) + 12 HC (g) ~ 4 PC|3(9) + 6H2(9)
AH° = -47.08 kJ
Wil the following actions favor a shift to the right side, to the left side, or have no such effect? ADD MORE P4

A

no effect

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15
Q

Consider the following system at equilibrium.
PA(s) + 12 HC (g) ~ 4 PC|3(9) + 6H2(9)
AH° = -47.08 kJ
Wil the following actions favor a shift to the right side, to the left side, or have no such effect? INCREASE H2 PRESSURE

A

left

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16
Q

Consider the following system at equilibrium.
PA(s) + 12 HC (g) ~ 4 PC|3(9) + 6H2(9)
AH° = -47.08 kJ
Wil the following actions favor a shift to the right side, to the left side, or have no such effect? ADD NE(G) TO INCREASE THE TOTAL PRESSURE IN THE SYSTEM

A

no effect

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17
Q

Consider the following system at equilibrium.
PA(s) + 12 HC (g) ~ 4 PC|3(9) + 6H2(9)
AH° = -47.08 kJ
Wil the following actions favor a shift to the right side, to the left side, or have no such effect? DECREASE THE VOLUME OF THE SYSTEM

A

right

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18
Q

Hydrobromic acid is a strong acid.

A

true

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19
Q

Chloride has no significant pul on H+ of H30+.

A

true

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20
Q

Water can completely dissociate HF.

21
Q

in pure water, [OH-] = 1.0 × 10^-14 M.

22
Q

The protonation of a base gives a conjugate acid.

23
Q

Acetate has no significant pul on H+ of H3O+.

24
Q

Oxalic acid is a weak acid.

25
in basic solution, pOH > pH.
false
26
a solution of pH 3 is more acidic than a solution of pH 4.
true
27
NO2^-is the conjugate base of nitric acid.
false
28
When ammonia dissolves ni water, every molecule of ammonia becomes protonated.
false
29
When ammonia dissolves ni water, every molecule of ammonia becomes protonated.
false
30
As [OH] increases, pH increases.
true
31
As pOH increases, [H+] decreases.
false
32
H2PO4^- and HPO4^2- are a conjugate pair.
true
33
Upon dissolving in water, hydrogen iodide wil protonate water.
true
34
Water molecules can pull on each other and break an O-H bond (at least to some extent).
true
35
Asolution of pH 6 is more basic than a solution of pOH 6.
false
36
Water can protonate a base and it can deprotonate an acid.
true
37
Bisulfate is the conjugate acid of sulfate.
true
38
In a weak acid solution, dilution favors dissociation.
true
39
perchloric acid is diprotic.
false
40
Water can deprotonate bisulfate ion (at least to some extent).
true
41
the Ka of H2PO4- is greater than the Ka of HPO4^2-
true
42
HClO, is a stronger acid than HCI
false
43
Amines are weak bases.
true
44
Protonated amines are weak acids.
true
45
Anions of weak, monoprotic acids are weak bases.
true
46
Acetate ion is a better base than cyanide ion.
false
47
Ammonia is a better base than phosphate ion.
false
48
Metal cations of 3+ charge are acidic.
true