Types of Volumetric Precipitation Methods v Flashcards
-named after Karl Friedrich Mohr
-for determining chloride content
MOHR Method
b. the chloride is titrated with AgNO3 solution
c. soluble chromate (K2CrO4) is
added as indicator
MOHR Method
This method is useful for determining chloride
in drinking water.
MOHR Method
- indirect or back titration procedure
- for determination of anions that
precipitate silver like Cl-, Br-, I-,
SCN
VOLHARD Method
is added
to form a film over the
precipitated AgCl
NITROBENZENE
makes use of adsorption
indicators
FAJANS Method
the endpoint is marked by
green suspension turning to
pink
FAJANS Method
is a type of titration involving
silver ions
Argentometry
precipitate organic nitrogen
compounds such as alkaloids,
amines
Sodium Tetraphenylboron Titrations
Application of Precipitation Methods
-salt content in crisps, ketchup
and food
-iodide in iodized salt
-silver content in coins
-sulfate content in mineral water
for metal determination
using EDTA
Complexation Methods
when a metal ion combines
with a molecule which can
donate electrons
Complex
combining molecule contains
two or more groups that donate electrons
Chelate
determination of metal in the
presence of another metal
Masking
suppress Al-EDTA
complex
Triethanolamine
