U2AoS1 - Redox Reactions Flashcards

(42 cards)

1
Q

What are Redox Reactions?

A

A reaction that involves the transfer of electrons.
Processes of oxidation and reduction

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2
Q

What are the types of redox reactions?

A
  • Addition/combination reaction
  • Decomposition reaction
  • Displacement reaction
  • Combustion reaction
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3
Q

What is an addition reaction?

A

A + B – C

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4
Q

What is a decomposition reaction?

A

c - A + B

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5
Q

What is a displacement reaction?

A

A + BC – B + AC

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6
Q

What is oxidation?

A

Loss of electrons

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7
Q

What is reduction?

A

Gain of electrons

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8
Q

Half equation

A

electrons shown as either a product or reactant depending on oxidation or reduction

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9
Q

Reductant

A

Substance that causes another to be reduced and itself oxidised

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10
Q

Oxidant

A

Substance which causes another to be oxidised and itself reduced

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11
Q

Overall balance equation

A

Shows products/reactants but not electrons

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12
Q

Ionic equation

A

Two half equations written together
- no spectator ions
- must be balanced when two added together

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13
Q

Conjugate redox pair

A

Pair differ by one or more electrons
Oxidised form written first

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14
Q

Are ionic compounds formed through redox reactions?

A

Transfer of electrons hence, yes

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15
Q

Covalent molecular compounds… are they redox?

A
  • can be involved despite shared
  • partial electron transfer, unequal sharing of electrons
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16
Q

Oxidation numbers

A

determines if a redox reaction has occured

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17
Q

Oxidation number increases

18
Q

Oxidation number decreases

19
Q

Oxidation number of free elements

20
Q

Oxidation number of ionic compounds

A

Charge of the ion

21
Q

Polyatomic oxidation numbers

A

Sum is equal to the charge on the ion

22
Q

Oxygen and Hydrogen Numbers

A

usually, -2 and +1

23
Q

UNDER ACIDIC CONDITIONS

A

KOHES
- key elements
- oxygen balanced by water
- hydrogen by H+ ions
- electrons added
- states

24
Q

Overall ionic equations

A
  • balance no.
  • add half equations
  • cancel species on both sides
25
Reactivity of metals
A will only replace B if A is more reactive. A is oxidised and B is reduced
26
Forwards Reaction
Reduction
27
Backwards Reaction
Oxidisation
28
Strong oxidants
accept electrons more readily
29
Strong reductants
donate protons more readily
30
What is a Galvanic Cell?
Converts chemical energy to electrical energy from spontaneous redox reactions taking place in the cell
31
What is a laboratory galvanic cell?
Reactants separated into half cells connected with wire and a salt bridge to complete the circuit and allow for movement of electrons
32
Half cells
contains a conjugate redox pair, electrodes must conduct electricity
33
Anode
negative polarity (oxidation) will decrease mass and increase color intensity
34
Cathode
positive polarity will increase in size
35
If conjugate redox pair is metal
metal electrode
36
If it does not contain metal
inert electrode (graphite or platnum) for fe4+ and sn 2+
37
If it is a gas
Gas electrode platinum used
38
Two electrolytes
Solution which contains free moving ions
39
Salt bridge
- connects/completes the circuit - provides ions to compensate for those lost/gained during a reation KNO3
40
Voltmeter
records voltage (potential difference) produced by cell
41
External circuit
electrodes+ wire
42
Internal circuit
salt bridge + electrodes