UCAS Mock Flashcards

(45 cards)

1
Q

What is the volume of one mole of a gas?

A

24dm-3 or 24000cm-1

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2
Q

Calculate gas volume using moles

A

Volume = moles x 24

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3
Q

Avogadros constant

A

6.02 x 10^23

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4
Q

Ideal gas equation

A

pV = nRT

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5
Q

Units for ideal gas equation

A

p = Pa
V = m^3
T = Kelvin

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6
Q

Calculating mean titre things to remember

A
  • only use concordant results (within 0.1cm^3 of each other)
  • don’t include the rough titre
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7
Q

% yield

A

Actual / theoretical

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8
Q

Oxidation number of group1

A

+1

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9
Q

Oxidation number of group 2

A

+2

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10
Q

Oxidation number of group 7 ions

A

-1 if alone but can be variable

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11
Q

Oxidation number of oxygen

A

-2 unless in peroxide

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12
Q

Oxidation number of hydrogen

A

+1 unless in a metal hydride

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13
Q

Oxidation number of fluorine

A

ALWAYS -1

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14
Q

Energy change

A

q = mcΔT (in joules)

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15
Q

Test for carbonate ions

A

Add nitric acid
- if positive test, there’s effervescence as CO2 is produced
- test gas with lime water to confirm

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16
Q

Test for sulfate ions

A

Add aqueous barium chloride
- positive test: white precipitate formed (BaSO4)

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17
Q

Test for halides

A

Add aqueous silver nitrate
- positive test: precipitate formed

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18
Q

How to identify the precipitate formed in halide test

A

White - silver chloride
Cream - silver bromide
Yellow - silver iodide

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19
Q

How to confirm halide tests if colours are difficult to determine

A

Dilute NH3: AgCl is soluble, AgBr and AgI are insoluble
Conc NH3: AgBr is soluble, AgI is insoluble

20
Q

Test for ammonium ions

A

Heat with NaOH(aq)
- positive test, OH- reacts with NH4+ forming NH3(g) which you test with damp indicator paper (alkaline)

21
Q

Group 2 + oxygen

A

Group 2 metal oxide

22
Q

Group 2 + water

A

Group 2 metal hydroxide + hydrogen

23
Q

Group 2 + dilute acid

A

Group 2 metal salt + hydrogen gas

24
Q

Group 2 oxide + water

A

(Group 2 ion)^2+ + 2OH-

25
How are group 2 reducing agents
Donate electrons, other species are reduced
26
Trend in group 2 reactivity
Increases down group Atomic radius and electron shielding increase (more shells) Less attraction between outer electron and nucleus
27
Solubility and PH trend in group 2 hydroxides
Increase down group
28
Solubility and PH trend in group 2 sulfates
Decreases down group
29
Uses of calcium hydroxide
Lime - neutralise acidic fam soil for crops
30
Medical uses of group 2
- indigestion tablets neutralise excess stomach acid (Mg(OH)2 = milk of magnesia and CaCO3) - barium meal for x-rays
31
Why are group 7 known as oxidising agents
Gain electrons causing other species to be reduced
32
Colour of halogens in water
Cl - pale green Br - orange I - brown
33
Colour of halogens in cyclohexane
Cl - pale green Br - orange I - purple/ violet
34
Displacement of halogens
Reactivity decreases down group - chlorine displaces bromine + iodine - bromine displaces iodine
35
Water purification using chlorine
Cl2 + H2O —> HClO + HCl - HClO acts as a weak bleach that kills bacteria
36
Water purification using chlorine
Cl2 + H2O —> HClO + HCl - HClO acts as a weak bleach that kills bacteria
37
Benefits and risks of using chlorine in the water purification
Benefits: – Cleans water makes it safe to drink Risks: – chlorine is a toxic gas, can react with hydrocarbons to form chlorinated hydrocarbons, which are suspected of causing cancer
38
Benefits and risks of using chlorine in the water purification
Benefits: – Cleans water makes it safe to drink Risks: – chlorine is a toxic gas, can react with hydrocarbons to form chlorinated hydrocarbons, which are suspected of causing cancer
39
Dissociation of a strong acid
irreversible reaction (One way reaction)
40
Dissociation of a weak acid
Reversible reaction
41
Acid + alkali
Salt + water
42
Metal oxide + acid
Salt + water
43
Metal hydroxide + acid
Salt + water
44
Metal carbonate + acid
Salt + water + carbon dioxide
45
Neutralisation ionic equation
OH-(aq) + H+(aq) —-> H2O(l)